Research output per year
Research output per year
Description
Neutron datasets from ISIS, RB1310009
The aim of this proposed study is to explore protic ionic liquids formed from by combining bis{(trifluoromethyl)sulfonyl}imidic acid (H[NTf2]) with imidazole and pyridine at different acid:base ratios from 2:1 through 1:1 to 1:2, in order to determine whether cluster or homoconjugated dimeric ([X···H···X] ) ions are formed in the acidic and basic regions of the phase space and to understand how such ions contribute to the overall liquid structure, viscosity changes and proton conductivity.
The aim of this proposed study is to explore protic ionic liquids formed from by combining bis{(trifluoromethyl)sulfonyl}imidic acid (H[NTf2]) with imidazole and pyridine at different acid:base ratios from 2:1 through 1:1 to 1:2, in order to determine whether cluster or homoconjugated dimeric ([X···H···X] ) ions are formed in the acidic and basic regions of the phase space and to understand how such ions contribute to the overall liquid structure, viscosity changes and proton conductivity.
| Date made available | 01 Mar 2016 |
|---|---|
| Publisher | STFC ISIS |
| Date of data production | 22 Feb 2013 - 01 Mar 2013 |
Research output
- 1 Article
-
Association and liquid structure of pyridine-acetic acid mixtures determined from neutron scattering using a ‘free proton’ EPSR simulation model
McCune, J. A., Turner, A. H., Coleman, F., White, C. M., Callear, S. K., Youngs, T. G. A., Swadzba-Kwasny, M. & Holbrey, J. D., 2015, In: Physical Chemistry Chemical Physics. 17, p. 6767-6777 11 p.Research output: Contribution to journal › Article › peer-review
Open AccessFile20 Citations (Scopus)858 Downloads (Pure)