Lawrence Hale - Research output - Queen's University Belfast

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3 Article
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2025
An operationally simple, regioselective, platinum-catalyzed hydroboration of unactivated alkynes
Hale, K. L. E., Roberts, D. D. & McLaughlin, M. G., 17 Mar 2025, In: European Journal of Organic Chemistry. 28, 11, 4 p., e202401355.
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On the divergent reactivity of allenylstannanes generated from the O-directed free radical hydrostannation reaction of (±)-trans-3-(2-phenylcyclopropyl)prop-2-yn-1-ol. EPR evidence for the reversible addition of Ph₃Sn radicals to vinyl triphenyltins
Hale, K. L. E., Fielding, A. J. & Hale, K. J., 07 May 2025, In: Organic & Biomolecular Chemistry. 23, 17, p. 4116-4130 15 p.
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Rate constants and Arrhenius parameters for H-atom abstraction from Bu₃SnH by the 2,2-dimethylvinyl radical in PhMe. Kinetic evidence for an entirely free radical mechanism for the O-directed hydrostannation of alkynols with stannanes and Et₃B/O₂
Watson, H. A., Hale, K. L. E., Marron, J. M., Manaviazar, S., Fielding, A. J. & Hale, K. J., 07 May 2025, In: Organic & Biomolecular Chemistry. 23, 17, p. 4106-4115 10 p.
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