(η5-Pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride

Sravan K. Bandaru; Andrew C. Marr; Graham C. Saunders

doi:10.3390/m1641

(η5-Pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride

Sravan K. Bandaru^*
, Andrew C. Marr
, Graham C. Saunders

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

103 Downloads (Pure)

Abstract

In this paper, we report (η5-pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride, 2, synthesized using a silver transfer agent generated from 1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolium bromide. Compound 2 was characterized using 1H and 19F NMR spectroscopy and mass spectrometry, and its structure was determined in a single-crystal X-ray diffraction study.

Original language	English
Article number	M1641
Journal	Molbank
Volume	2023
Issue number	2
Early online date	08 May 2023
DOIs	https://doi.org/10.3390/m1641
Publication status	Published - Jun 2023

Keywords

Organic Chemistry
Physical and Theoretical Chemistry
Biochemistry

Access to Document

10.3390/m1641Licence: CC BY

(η5-Pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride
Copyright 2023 the authors. This is an open access article published under a Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
Final published version, 1.49 MBLicence: CC BY

Cite this

@article{6012f228b01442ddb4807cc93119e440,

title = "(η5-Pentamethylcyclopentadienyl)iridium\{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene\}dichloride",

abstract = "In this paper, we report (η5-pentamethylcyclopentadienyl)iridium\{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene\}dichloride, 2, synthesized using a silver transfer agent generated from 1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolium bromide. Compound 2 was characterized using 1H and 19F NMR spectroscopy and mass spectrometry, and its structure was determined in a single-crystal X-ray diffraction study.",

keywords = "Organic Chemistry, Physical and Theoretical Chemistry, Biochemistry",

author = "Bandaru, \{Sravan K.\} and Marr, \{Andrew C.\} and Saunders, \{Graham C.\}",

year = "2023",

month = jun,

doi = "10.3390/m1641",

language = "English",

volume = "2023",

journal = "Molbank",

issn = "1422-8599",

publisher = "Multidisciplinary Digital Publishing Institute",

number = "2",

}

TY - JOUR

T1 - (η5-Pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride

AU - Bandaru, Sravan K.

AU - Marr, Andrew C.

AU - Saunders, Graham C.

PY - 2023/6

Y1 - 2023/6

N2 - In this paper, we report (η5-pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride, 2, synthesized using a silver transfer agent generated from 1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolium bromide. Compound 2 was characterized using 1H and 19F NMR spectroscopy and mass spectrometry, and its structure was determined in a single-crystal X-ray diffraction study.

AB - In this paper, we report (η5-pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride, 2, synthesized using a silver transfer agent generated from 1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolium bromide. Compound 2 was characterized using 1H and 19F NMR spectroscopy and mass spectrometry, and its structure was determined in a single-crystal X-ray diffraction study.

KW - Organic Chemistry

KW - Physical and Theoretical Chemistry

KW - Biochemistry

U2 - 10.3390/m1641

DO - 10.3390/m1641

M3 - Article

SN - 1422-8599

VL - 2023

JO - Molbank

JF - Molbank

IS - 2

M1 - M1641

ER -

(η5-Pentamethylcyclopentadienyl)iridium{1,3-bis(2,3,4,5,6-pentafluorobenzyl)imidazolin-2-ylidene}dichloride

Abstract

Keywords

Access to Document

Fingerprint

Cite this