1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate: a novel ionic liquid containing a rigid, planar energetic anion

A.R. Katritzky; S. Singh; K. Kirichenko; John Holbrey; M. Smiglak; W.M. Reichert; R.D. Rogers

doi:10.1039/b414683b

1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate: a novel ionic liquid containing a rigid, planar energetic anion

A.R. Katritzky, S. Singh, K. Kirichenko, John Holbrey, M. Smiglak, W.M. Reichert, R.D. Rogers

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

117 Citations (Scopus)

Abstract

The novel ionic liquid, 1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate has been synthesized and exhibits an unexpectedly low melting point (35 degreesC) considering the size and shape of the rigid, planar anion; analogous tetraalkylammonium salts (methyl, ethyl and n-butyl) have also been prepared and the tetraethylammonium example was characterized by single crystal X-ray diffraction.

Original language	English
Pages (from-to)	868-870
Number of pages	3
Journal	Chemical Communications
Issue number	7
DOIs	https://doi.org/10.1039/b414683b
Publication status	Published - 21 Feb 2005

ASJC Scopus subject areas

General Chemistry

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title = "1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate: a novel ionic liquid containing a rigid, planar energetic anion",

abstract = "The novel ionic liquid, 1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate has been synthesized and exhibits an unexpectedly low melting point (35 degreesC) considering the size and shape of the rigid, planar anion; analogous tetraalkylammonium salts (methyl, ethyl and n-butyl) have also been prepared and the tetraethylammonium example was characterized by single crystal X-ray diffraction.",

author = "A.R. Katritzky and S. Singh and K. Kirichenko and John Holbrey and M. Smiglak and W.M. Reichert and R.D. Rogers",

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AU - Katritzky, A.R.

AU - Singh, S.

AU - Kirichenko, K.

AU - Holbrey, John

AU - Smiglak, M.

AU - Reichert, W.M.

AU - Rogers, R.D.

PY - 2005/2/21

Y1 - 2005/2/21

N2 - The novel ionic liquid, 1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate has been synthesized and exhibits an unexpectedly low melting point (35 degreesC) considering the size and shape of the rigid, planar anion; analogous tetraalkylammonium salts (methyl, ethyl and n-butyl) have also been prepared and the tetraethylammonium example was characterized by single crystal X-ray diffraction.

AB - The novel ionic liquid, 1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate has been synthesized and exhibits an unexpectedly low melting point (35 degreesC) considering the size and shape of the rigid, planar anion; analogous tetraalkylammonium salts (methyl, ethyl and n-butyl) have also been prepared and the tetraethylammonium example was characterized by single crystal X-ray diffraction.

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DO - 10.1039/b414683b

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ER -

1-butyl-3-methylimidazolium 3,5-dinitro-1,2,4-triazolate: a novel ionic liquid containing a rigid, planar energetic anion

Abstract

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