Abstract
| Original language | English |
|---|---|
| Article number | 193823 |
| Number of pages | 10 |
| Journal | Journal of Chemical Physics |
| Volume | 148 |
| DOIs | |
| Publication status | Published - 12 Feb 2018 |
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A comparison of choline:urea and choline:oxalic acid deep eutectic solvents at 338 K. / Gilmore, Mark; Moura, Leila; Turner, Adam; Swadzba-Kwasny, Malgorzata; Callear, Samantha; McCune, Jade A.; Scherman, Oren A.; Holbrey, John.
In: Journal of Chemical Physics, Vol. 148, 193823, 12.02.2018.Research output: Contribution to journal › Article
TY - JOUR
T1 - A comparison of choline:urea and choline:oxalic acid deep eutectic solvents at 338 K
AU - Gilmore, Mark
AU - Moura, Leila
AU - Turner, Adam
AU - Swadzba-Kwasny, Malgorzata
AU - Callear, Samantha
AU - McCune, Jade A.
AU - Scherman, Oren A.
AU - Holbrey, John
PY - 2018/2/12
Y1 - 2018/2/12
N2 - 1:2 choline chloride:urea and 1:1 choline chloride:oxalic acid deep eutectic solvents are compared at 338 K using liquid-phase neutron diffraction with H/D isotopic substitution to obtain differential neutron scattering cross sections and fitting of models to the experimental data using Empirical Potential Structure Refinement. In comparison to the previously reported study of choline chloride:urea at 303 K, we observed significant weakening and lengthening of choline–OH· · · Cl and choline–OH· · · hydrogen-bond acceptor correlations.
AB - 1:2 choline chloride:urea and 1:1 choline chloride:oxalic acid deep eutectic solvents are compared at 338 K using liquid-phase neutron diffraction with H/D isotopic substitution to obtain differential neutron scattering cross sections and fitting of models to the experimental data using Empirical Potential Structure Refinement. In comparison to the previously reported study of choline chloride:urea at 303 K, we observed significant weakening and lengthening of choline–OH· · · Cl and choline–OH· · · hydrogen-bond acceptor correlations.
U2 - 10.1063/1.5010246
DO - 10.1063/1.5010246
M3 - Article
VL - 148
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
M1 - 193823
ER -