Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O-2 at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction.
|Number of pages||5|
|Publication status||Published - 1997|
- falling initial distributions of deuterio-isomers
- Pd catalysts
- novel supports and pretreatments
- cyclopentane/D-2 exchange