A dramatic shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction on palladium catalysts

G Fitzsimons; C Hardacre; WR Patterson; JJ Rooney; JKA Clarke; MR Smith; RM Ormerod

A dramatic shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction on palladium catalysts

G Fitzsimons, C Hardacre, WR Patterson, JJ Rooney, JKA Clarke, MR Smith, RM Ormerod

Research output: Contribution to journal › Article › peer-review

Abstract

Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O-2 at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction.

Original language	English
Pages (from-to)	187-191
Number of pages	5
Journal	Catalysis Letters
Volume	45
Issue number	3-4
Publication status	Published - 1997

Keywords

X-RAY-ABSORPTION
SUPPORT
SPECTROSCOPY
falling initial distributions of deuterio-isomers
DEUTERIUM
Pd catalysts
novel supports and pretreatments
cyclopentane/D-2 exchange
EXAFS
PARTICLE-SIZE
SITES

Cite this

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title = "A dramatic shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction on palladium catalysts",

abstract = "Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O-2 at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction.",

keywords = "X-RAY-ABSORPTION, SUPPORT, SPECTROSCOPY, falling initial distributions of deuterio-isomers, DEUTERIUM, Pd catalysts, novel supports and pretreatments, cyclopentane/D-2 exchange, EXAFS, PARTICLE-SIZE, SITES",

author = "G Fitzsimons and C Hardacre and WR Patterson and JJ Rooney and JKA Clarke and MR Smith and RM Ormerod",

year = "1997",

language = "English",

volume = "45",

pages = "187--191",

journal = "Catalysis Letters",

issn = "1011-372X",

publisher = "Springer",

number = "3-4",

}

TY - JOUR

T1 - A dramatic shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction on palladium catalysts

AU - Fitzsimons, G

AU - Hardacre, C

AU - Patterson, WR

AU - Rooney, JJ

AU - Clarke, JKA

AU - Smith, MR

AU - Ormerod, RM

PY - 1997

Y1 - 1997

N2 - Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O-2 at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction.

AB - Electron deficient active sites in Pd catalysts, either as films or on supports, are deliberately generated by calcining in O-2 at high temperature followed by the mildest possible reduction (with the reaction mixture itself), and are manifested by a marked shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction.

KW - X-RAY-ABSORPTION

KW - SUPPORT

KW - SPECTROSCOPY

KW - falling initial distributions of deuterio-isomers

KW - DEUTERIUM

KW - Pd catalysts

KW - novel supports and pretreatments

KW - cyclopentane/D-2 exchange

KW - EXAFS

KW - PARTICLE-SIZE

KW - SITES

M3 - Article

SN - 1011-372X

VL - 45

SP - 187

EP - 191

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

A dramatic shift from multiple to simple exchange in the cyclopentane/D-2 probe reaction on palladium catalysts

Abstract

Keywords

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