A facile, novel way to prepare anionic, neutral and cationic gold(I) complexes

José Vicente*, María Teresa Chicote, Isabel Saura-Llamas, María Cristina Lagunas

*Corresponding author for this work

Research output: Contribution to journalArticle

50 Citations (Scopus)

Abstract

The complex ppn[Au(acac)2] 1 can be obtained by reacting ppn[AuCl2] with [TI(acac)] in 1:2 molar ratio, and complex 1 reacts with compounds of the type RH in which H has some acidic character to give the corresponding [AuR2]- species; RH = CH2(CN) 2 2, CH2(CO2Me)2 3, CH 2(CN)CO2Me 4, Me3SiCCH 5, 2-SH-C 5H4N 6, AuR RH = CH2(PPh2) 2, 7, or [AuR2]+ RH = [(4-MeC6H 4)3PCH2C5H4N-2]ClO 4 8.

Original languageEnglish
Pages (from-to)915-916
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number12
DOIs
Publication statusPublished - 01 Dec 1992
Externally publishedYes

ASJC Scopus subject areas

  • Molecular Medicine

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