A facile, novel way to prepare anionic, neutral and cationic gold(I) complexes

José Vicente; María Teresa Chicote; Isabel Saura-Llamas; María Cristina Lagunas

doi:10.1039/C39920000915

A facile, novel way to prepare anionic, neutral and cationic gold(I) complexes

José Vicente^*, María Teresa Chicote, Isabel Saura-Llamas, María Cristina Lagunas

^*Corresponding author for this work

Research output: Contribution to journal › Article

50 Citations (Scopus)

Abstract

The complex ppn[Au(acac)₂] 1 can be obtained by reacting ppn[AuCl₂] with [TI(acac)] in 1:2 molar ratio, and complex 1 reacts with compounds of the type RH in which H has some acidic character to give the corresponding [AuR₂]^- species; RH = CH₂(CN) ₂ 2, CH₂(CO₂Me)₂ 3, CH ₂(CN)CO₂Me 4, Me₃SiCCH 5, 2-SH-C ₅H₄N 6, AuR RH = CH₂(PPh₂) ₂, 7, or [AuR₂]⁺ RH = [(4-MeC₆H ₄)₃PCH₂C₅H₄N-2]ClO ₄ 8.

Original language	English
Pages (from-to)	915-916
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/C39920000915
Publication status	Published - 01 Dec 1992
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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Vicente, J., Chicote, M. T., Saura-Llamas, I., & Lagunas, M. C. (1992). A facile, novel way to prepare anionic, neutral and cationic gold(I) complexes. Journal of the Chemical Society, Chemical Communications, (12), 915-916. https://doi.org/10.1039/C39920000915

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title = "A facile, novel way to prepare anionic, neutral and cationic gold(I) complexes",

abstract = "The complex ppn[Au(acac)2] 1 can be obtained by reacting ppn[AuCl2] with [TI(acac)] in 1:2 molar ratio, and complex 1 reacts with compounds of the type RH in which H has some acidic character to give the corresponding [AuR2]- species; RH = CH2(CN) 2 2, CH2(CO2Me)2 3, CH 2(CN)CO2Me 4, Me3SiCCH 5, 2-SH-C 5H4N 6, AuR RH = CH2(PPh2) 2, 7, or [AuR2]+ RH = [(4-MeC6H 4)3PCH2C5H4N-2]ClO 4 8.",

author = "Jos{\'e} Vicente and Chicote, {Mar{\'i}a Teresa} and Isabel Saura-Llamas and Lagunas, {Mar{\'i}a Cristina}",

year = "1992",

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doi = "10.1039/C39920000915",

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T1 - A facile, novel way to prepare anionic, neutral and cationic gold(I) complexes

AU - Vicente, José

AU - Chicote, María Teresa

AU - Saura-Llamas, Isabel

AU - Lagunas, María Cristina

PY - 1992/12/1

Y1 - 1992/12/1

N2 - The complex ppn[Au(acac)2] 1 can be obtained by reacting ppn[AuCl2] with [TI(acac)] in 1:2 molar ratio, and complex 1 reacts with compounds of the type RH in which H has some acidic character to give the corresponding [AuR2]- species; RH = CH2(CN) 2 2, CH2(CO2Me)2 3, CH 2(CN)CO2Me 4, Me3SiCCH 5, 2-SH-C 5H4N 6, AuR RH = CH2(PPh2) 2, 7, or [AuR2]+ RH = [(4-MeC6H 4)3PCH2C5H4N-2]ClO 4 8.

AB - The complex ppn[Au(acac)2] 1 can be obtained by reacting ppn[AuCl2] with [TI(acac)] in 1:2 molar ratio, and complex 1 reacts with compounds of the type RH in which H has some acidic character to give the corresponding [AuR2]- species; RH = CH2(CN) 2 2, CH2(CO2Me)2 3, CH 2(CN)CO2Me 4, Me3SiCCH 5, 2-SH-C 5H4N 6, AuR RH = CH2(PPh2) 2, 7, or [AuR2]+ RH = [(4-MeC6H 4)3PCH2C5H4N-2]ClO 4 8.

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