A highly efficient synthetic procedure for deuteriating imidazoles and imidazolium salts

Christopher Hardacre; John Holbrey; S.E.J. McMath

A highly efficient synthetic procedure for deuteriating imidazoles and imidazolium salts

Christopher Hardacre, John Holbrey, S.E.J. McMath

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

75 Citations (Scopus)

Abstract

Both substituted imidazoles and 1,3-dialkylimidazolium salts can be fully deuteriated on the heterocyclic ring using D2O over heterogeneous Pd catalysts: deuteriated 1-alkyl-3-methylimidazolium chloride and hexafluorophosphate ionic liquids can also be prepared in good yields utilising readily available and relatively low cost sources of deuterium.

Original language	English
Pages (from-to)	367-368
Number of pages	2
Journal	Chemical Communications
Volume	*
Issue number	4
Publication status	Published - 21 Feb 2001

ASJC Scopus subject areas

General Chemistry

Cite this

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title = "A highly efficient synthetic procedure for deuteriating imidazoles and imidazolium salts",

abstract = "Both substituted imidazoles and 1,3-dialkylimidazolium salts can be fully deuteriated on the heterocyclic ring using D2O over heterogeneous Pd catalysts: deuteriated 1-alkyl-3-methylimidazolium chloride and hexafluorophosphate ionic liquids can also be prepared in good yields utilising readily available and relatively low cost sources of deuterium.",

author = "Christopher Hardacre and John Holbrey and S.E.J. McMath",

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T1 - A highly efficient synthetic procedure for deuteriating imidazoles and imidazolium salts

AU - Hardacre, Christopher

AU - Holbrey, John

AU - McMath, S.E.J.

PY - 2001/2/21

Y1 - 2001/2/21

N2 - Both substituted imidazoles and 1,3-dialkylimidazolium salts can be fully deuteriated on the heterocyclic ring using D2O over heterogeneous Pd catalysts: deuteriated 1-alkyl-3-methylimidazolium chloride and hexafluorophosphate ionic liquids can also be prepared in good yields utilising readily available and relatively low cost sources of deuterium.

AB - Both substituted imidazoles and 1,3-dialkylimidazolium salts can be fully deuteriated on the heterocyclic ring using D2O over heterogeneous Pd catalysts: deuteriated 1-alkyl-3-methylimidazolium chloride and hexafluorophosphate ionic liquids can also be prepared in good yields utilising readily available and relatively low cost sources of deuterium.

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M3 - Article

SN - 1359-7345

VL - *

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JO - Chemical Communications

JF - Chemical Communications

IS - 4

ER -

A highly efficient synthetic procedure for deuteriating imidazoles and imidazolium salts

Abstract

ASJC Scopus subject areas

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