A new class of AuI2AgI cluster

José Vicente; María Teresa Chicote; María Cristina Lagunas; Peter G. Jones

doi:10.1039/C39910001730

A new class of Au^I₂Ag^I cluster

José Vicente^*, María Teresa Chicote, María Cristina Lagunas, Peter G. Jones

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

The reaction of the gold(I) ylide complex [(AuPPh₃) ₂{μ-C(PPh₃)(C₅H₄N-2)}]ClO ₄ with AgNO₃ yields the mixed metal complex [(AuPPh ₃)₂{μ-C(PPh₃)(C₅H ₄N-2)}{μ-Ag(η²-O₂NO)(OClO₃)], the central moiety of which consists of a loose Au₂Ag cluster with metal-metal contacts ca. 3 Å.

Original language	English
Pages (from-to)	1730-1731
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	24
DOIs	https://doi.org/10.1039/C39910001730
Publication status	Published - 01 Dec 1991
Externally published	Yes

ASJC Scopus subject areas

Molecular Medicine

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title = "A new class of AuI2AgI cluster",

abstract = "The reaction of the gold(I) ylide complex [(AuPPh3) 2{μ-C(PPh3)(C5H4N-2)}]ClO 4 with AgNO3 yields the mixed metal complex [(AuPPh 3)2{μ-C(PPh3)(C5H 4N-2)}{μ-Ag(η2-O2NO)(OClO3)], the central moiety of which consists of a loose Au2Ag cluster with metal-metal contacts ca. 3 {\AA}.",

author = "Jos{\'e} Vicente and Chicote, {Mar{\'i}a Teresa} and Lagunas, {Mar{\'i}a Cristina} and Jones, {Peter G.}",

year = "1991",

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doi = "10.1039/C39910001730",

language = "English",

pages = "1730--1731",

journal = "Journal of the Chemical Society, Chemical Communications",

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TY - JOUR

T1 - A new class of AuI2AgI cluster

AU - Vicente, José

AU - Chicote, María Teresa

AU - Lagunas, María Cristina

AU - Jones, Peter G.

PY - 1991/12/1

Y1 - 1991/12/1

N2 - The reaction of the gold(I) ylide complex [(AuPPh3) 2{μ-C(PPh3)(C5H4N-2)}]ClO 4 with AgNO3 yields the mixed metal complex [(AuPPh 3)2{μ-C(PPh3)(C5H 4N-2)}{μ-Ag(η2-O2NO)(OClO3)], the central moiety of which consists of a loose Au2Ag cluster with metal-metal contacts ca. 3 Å.

AB - The reaction of the gold(I) ylide complex [(AuPPh3) 2{μ-C(PPh3)(C5H4N-2)}]ClO 4 with AgNO3 yields the mixed metal complex [(AuPPh 3)2{μ-C(PPh3)(C5H 4N-2)}{μ-Ag(η2-O2NO)(OClO3)], the central moiety of which consists of a loose Au2Ag cluster with metal-metal contacts ca. 3 Å.

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U2 - 10.1039/C39910001730

DO - 10.1039/C39910001730

M3 - Article

AN - SCOPUS:37049067974

SN - 0022-4936

SP - 1730

EP - 1731

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 24

ER -

A new class of Au^I₂Ag^I cluster

Abstract

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