A New Stereocontrolled Synthetic Route to (-)-Echinosporin from D-Glucose via Padwa Allenylsulfone [3+2]-Anionic Cycloadditive Elimination

Jakub T Flasz, Karl J Hale

Research output: Contribution to journalArticle

18 Citations (Scopus)

Abstract

A new formal total synthesis of (-)-echinosporin has been developed based upon the Padwa [3 + 2]-cycloadditive elimination reaction of allenylsulfone 4 with the D-glucose-derived enone 14 which provides cycloadduct 12.
Original languageEnglish
Pages (from-to)3024-3027
Number of pages4
JournalOrganic Letters
Volume14
Issue number12
Early online date30 May 2012
DOIs
Publication statusPublished - 15 Jun 2012

ASJC Scopus subject areas

  • Organic Chemistry
  • Physical and Theoretical Chemistry
  • Biochemistry

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