A Non-catalytic Deep Desulphurization Process using Hydrodynamic Cavitation

Nalinee B. Suryawanshi, Vinay M. Bhandari, Laxmi Gayatri Sorokhaibam, Vivek Ranade

Research output: Contribution to journalArticle

18 Citations (Scopus)
224 Downloads (Pure)

Abstract

A novel approach is developed for desulphurization of fuels or organics without use of catalyst. In this process, organic and aqueous phases are mixed in a predefined manner under ambient conditions and passed through a cavitating device. Vapor cavities formed in the cavitating device are then collapsed which generate (in-situ) oxidizing species which react with the sulphur moiety resulting in the removal of sulphur from the organic phase. In this work, vortex diode was used as a cavitating device. Three organic solvents (n-octane, toluene and n-octanol) containing known amount of a model sulphur compound (thiophene) up to initial concentrations of 500 ppm were used to verify the proposed method. A very high removal of sulphur content to the extent of 100% was demonstrated. The nature of organic phase and the ratio of aqueous to organic phase were found to be the most important process parameters. The results were also verified and substantiated using commercial diesel as a solvent. The developed process has great potential for deep of various organics, in general, and for transportation fuels, in particular.
Original languageEnglish
Article number33021
Number of pages8
JournalNature Scientific Reports
Volume6
DOIs
Publication statusPublished - 08 Sep 2016

Fingerprint

Sulfur
Cavitation
Hydrodynamics
1-Octanol
Sulfur Compounds
Thiophenes
Toluene
Organic solvents
Diodes
Vortex flow
Vapors
Catalysts

Cite this

Suryawanshi, Nalinee B. ; Bhandari, Vinay M. ; Sorokhaibam, Laxmi Gayatri ; Ranade, Vivek. / A Non-catalytic Deep Desulphurization Process using Hydrodynamic Cavitation. In: Nature Scientific Reports. 2016 ; Vol. 6.
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A Non-catalytic Deep Desulphurization Process using Hydrodynamic Cavitation. / Suryawanshi, Nalinee B.; Bhandari, Vinay M.; Sorokhaibam, Laxmi Gayatri; Ranade, Vivek.

In: Nature Scientific Reports, Vol. 6, 33021, 08.09.2016.

Research output: Contribution to journalArticle

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AB - A novel approach is developed for desulphurization of fuels or organics without use of catalyst. In this process, organic and aqueous phases are mixed in a predefined manner under ambient conditions and passed through a cavitating device. Vapor cavities formed in the cavitating device are then collapsed which generate (in-situ) oxidizing species which react with the sulphur moiety resulting in the removal of sulphur from the organic phase. In this work, vortex diode was used as a cavitating device. Three organic solvents (n-octane, toluene and n-octanol) containing known amount of a model sulphur compound (thiophene) up to initial concentrations of 500 ppm were used to verify the proposed method. A very high removal of sulphur content to the extent of 100% was demonstrated. The nature of organic phase and the ratio of aqueous to organic phase were found to be the most important process parameters. The results were also verified and substantiated using commercial diesel as a solvent. The developed process has great potential for deep of various organics, in general, and for transportation fuels, in particular.

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