Acoustic and volumetric properties of aqueous solutions of imidazolium based ionic liquids at 298.15 K

Ramesh Gardas; D.H. Dagade; S.S. Terdale; J.A.P. Coutinho; K.J. Patil

doi:10.1016/j.jct.2007.10.007

Acoustic and volumetric properties of aqueous solutions of imidazolium based ionic liquids at 298.15 K

Ramesh Gardas, D.H. Dagade, S.S. Terdale, J.A.P. Coutinho, K.J. Patil

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

66 Citations (Scopus)

Abstract

The experimental measurements of the speed of sound and density of aqueous solutions of imidazolium based ionic liquids (IL) in the concentration range of 0.05 mol · kg-1 to 0.5 mol · kg-1 at T = 298.15 K are reported. The data are used to obtain the isentropic compressibility (ßS) of solutions. The apparent molar volume (phiV) and compressibility (phiKS) of ILs are evaluated at different concentrations. The data of limiting partial molar volume and compressibility of IL and their concentration variation are examined to evaluate the effect due to IL–water and IL–IL interactions. The results have been discussed in terms of hydrophobic hydration, hydrophobic interactions, and water structural changes in aqueous medium.

Original language	English
Pages (from-to)	695-701
Number of pages	7
Journal	The Journal of Chemical Thermodynamics
Volume	40 (4)
Issue number	4
DOIs	https://doi.org/10.1016/j.jct.2007.10.007
Publication status	Published - Apr 2008

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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10.1016/j.jct.2007.10.007

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title = "Acoustic and volumetric properties of aqueous solutions of imidazolium based ionic liquids at 298.15 K",

abstract = "The experimental measurements of the speed of sound and density of aqueous solutions of imidazolium based ionic liquids (IL) in the concentration range of 0.05 mol · kg-1 to 0.5 mol · kg-1 at T = 298.15 K are reported. The data are used to obtain the isentropic compressibility ({\ss}S) of solutions. The apparent molar volume (phiV) and compressibility (phiKS) of ILs are evaluated at different concentrations. The data of limiting partial molar volume and compressibility of IL and their concentration variation are examined to evaluate the effect due to IL–water and IL–IL interactions. The results have been discussed in terms of hydrophobic hydration, hydrophobic interactions, and water structural changes in aqueous medium.",

author = "Ramesh Gardas and D.H. Dagade and S.S. Terdale and J.A.P. Coutinho and K.J. Patil",

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T1 - Acoustic and volumetric properties of aqueous solutions of imidazolium based ionic liquids at 298.15 K

AU - Gardas, Ramesh

AU - Dagade, D.H.

AU - Terdale, S.S.

AU - Coutinho, J.A.P.

AU - Patil, K.J.

PY - 2008/4

Y1 - 2008/4

N2 - The experimental measurements of the speed of sound and density of aqueous solutions of imidazolium based ionic liquids (IL) in the concentration range of 0.05 mol · kg-1 to 0.5 mol · kg-1 at T = 298.15 K are reported. The data are used to obtain the isentropic compressibility (ßS) of solutions. The apparent molar volume (phiV) and compressibility (phiKS) of ILs are evaluated at different concentrations. The data of limiting partial molar volume and compressibility of IL and their concentration variation are examined to evaluate the effect due to IL–water and IL–IL interactions. The results have been discussed in terms of hydrophobic hydration, hydrophobic interactions, and water structural changes in aqueous medium.

AB - The experimental measurements of the speed of sound and density of aqueous solutions of imidazolium based ionic liquids (IL) in the concentration range of 0.05 mol · kg-1 to 0.5 mol · kg-1 at T = 298.15 K are reported. The data are used to obtain the isentropic compressibility (ßS) of solutions. The apparent molar volume (phiV) and compressibility (phiKS) of ILs are evaluated at different concentrations. The data of limiting partial molar volume and compressibility of IL and their concentration variation are examined to evaluate the effect due to IL–water and IL–IL interactions. The results have been discussed in terms of hydrophobic hydration, hydrophobic interactions, and water structural changes in aqueous medium.

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U2 - 10.1016/j.jct.2007.10.007

DO - 10.1016/j.jct.2007.10.007

M3 - Article

VL - 40 (4)

SP - 695

EP - 701

JO - The Journal of Chemical Thermodynamics

JF - The Journal of Chemical Thermodynamics

SN - 0021-9614

IS - 4

ER -

Acoustic and volumetric properties of aqueous solutions of imidazolium based ionic liquids at 298.15 K

Abstract

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