Amination and dehydration of 1,3-propanediol by hydrogen transfer: reactions of a bio-renewable platform chemical

S.D. Lacroix; Annie Pennycook; Shifang Liu; T.T. Eisenhart; Andrew Marr

doi:10.1039/c1cy00339a

Amination and dehydration of 1,3-propanediol by hydrogen transfer: reactions of a bio-renewable platform chemical

S.D. Lacroix, Annie Pennycook, Shifang Liu, T.T. Eisenhart, Andrew Marr

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

1,3-propanediol was subjected to a range of amination conditions. The N-heterocyclic carbene piano stool complex [Cp*IrCl2(bmim)] was found to be a good catalyst for amination and dehydration in toluene or ionic liquid; product compositions could be tuned by altering the ratio of diol to amine.

Original language	English
Pages (from-to)	288-290
Number of pages	3
Journal	Catalysis Science & Technology
Volume	2
Issue number	2
Early online date	17 Oct 2011
DOIs	https://doi.org/10.1039/c1cy00339a
Publication status	Published - Feb 2012

ASJC Scopus subject areas

Catalysis

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

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10.1039/c1cy00339a

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title = "Amination and dehydration of 1,3-propanediol by hydrogen transfer: reactions of a bio-renewable platform chemical",

abstract = "1,3-propanediol was subjected to a range of amination conditions. The N-heterocyclic carbene piano stool complex [Cp*IrCl2(bmim)] was found to be a good catalyst for amination and dehydration in toluene or ionic liquid; product compositions could be tuned by altering the ratio of diol to amine.",

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AU - Eisenhart, T.T.

AU - Marr, Andrew

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AB - 1,3-propanediol was subjected to a range of amination conditions. The N-heterocyclic carbene piano stool complex [Cp*IrCl2(bmim)] was found to be a good catalyst for amination and dehydration in toluene or ionic liquid; product compositions could be tuned by altering the ratio of diol to amine.

U2 - 10.1039/c1cy00339a

DO - 10.1039/c1cy00339a

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ER -

Amination and dehydration of 1,3-propanediol by hydrogen transfer: reactions of a bio-renewable platform chemical

Abstract

ASJC Scopus subject areas

UN SDGs

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