Amphiphilic terpyridine complexes of ruthenium and rhodium displaying lyotropic mesomorphism

John D. Holbrey*, Gordon J.T. Tiddy, Duncan W. Bruce

*Corresponding author for this work

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

New 4′-alkyl-substituted 2,2′:6′,2″-terpyridine (4′R-terpy) compounds have been synthesised from 4′-methyl-2,2′:6′,2″-terpyridine and an appropriate 1-bromoalkane and complexed with ruthenium and rhodium to yield new bis(terpyridine) complexes [Ru(terpy)(4′R-terpy)]2+ (R = C19H39 or C31H63) and [Rh(terpy)(4′R-terpy)]3+ (R = C19H39) as chloride and hexafluorophosphate salts. These complexes are amphiphilic being structurally related to surfactant tris(bipyridine)ruthenium complexes. Both ruthenium and rhodium complexes with R = C19H39 and chloride counter ions show lyotropic mesomorphism in water, and the ruthenium complex with R = C31H63 shows mesophase formation in ethylene glycol.

Original languageEnglish
Pages (from-to)1769-1774
Number of pages6
JournalJournal of the Chemical Society, Dalton Transactions
Issue number11
DOIs
Publication statusPublished - 01 Dec 1995

ASJC Scopus subject areas

  • Chemistry(all)

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