An alkyne hydrosilylation-Hiyama coupling approach to highly functionalised 1,3-dienes

Catherine A. McAdam; Mark G. McLaughlin; Matthew J. Cook

doi:10.1039/C5QO00002E

An alkyne hydrosilylation-Hiyama coupling approach to highly functionalised 1,3-dienes

Catherine A. McAdam, Mark G. McLaughlin, Matthew J. Cook^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

A high yielding and robust protocol for the stereodefined synthesis of 1,3-dienes has been established through a hydrosilylation–Hiyama coupling strategy. In all cases the products were formed as single E,E isomers and conditions are tolerant of a wide range of functional groups not compatible with other methods.

Original language	English
Pages (from-to)	510-514
Number of pages	5
Journal	Organic Chemistry Frontiers
Volume	2
Issue number	5
Early online date	17 Mar 2015
DOIs	https://doi.org/10.1039/C5QO00002E
Publication status	Published - 01 May 2015

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title = "An alkyne hydrosilylation-Hiyama coupling approach to highly functionalised 1,3-dienes",

abstract = "A high yielding and robust protocol for the stereodefined synthesis of 1,3-dienes has been established through a hydrosilylation–Hiyama coupling strategy. In all cases the products were formed as single E,E isomers and conditions are tolerant of a wide range of functional groups not compatible with other methods.",

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AB - A high yielding and robust protocol for the stereodefined synthesis of 1,3-dienes has been established through a hydrosilylation–Hiyama coupling strategy. In all cases the products were formed as single E,E isomers and conditions are tolerant of a wide range of functional groups not compatible with other methods.

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An alkyne hydrosilylation-Hiyama coupling approach to highly functionalised 1,3-dienes

Abstract

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