Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 32-46 |
| Number of pages | 15 |
| Journal | IONIC LIQUIDS IIIA: FUNDAMENTALS, PROGRESS, CHALLENGES, AND OPPORTUNITIES, PROPERTIES AND STRUCTURE |
| Volume | 901 |
| Publication status | Published - 2005 |
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An EXAFS, X-ray diffraction, and electrochemical investigation of 1-alkyl-3-methylimidazolium salts of [{UO2(NO3)(2)}(2)(mu(4)-C2O4)](2-). / Bradley, A.E.; Hardacre, Christopher; Nieuwenhuyzen, Mark; Pitner, W.R.; Sanders, D.; Seddon, Kenneth; Thied, R.C.
In: IONIC LIQUIDS IIIA: FUNDAMENTALS, PROGRESS, CHALLENGES, AND OPPORTUNITIES, PROPERTIES AND STRUCTURE, Vol. 901, 2005, p. 32-46.Research output: Contribution to journal › Article
TY - JOUR
T1 - An EXAFS, X-ray diffraction, and electrochemical investigation of 1-alkyl-3-methylimidazolium salts of [{UO2(NO3)(2)}(2)(mu(4)-C2O4)](2-)
AU - Bradley, A.E.
AU - Hardacre, Christopher
AU - Nieuwenhuyzen, Mark
AU - Pitner, W.R.
AU - Sanders, D.
AU - Seddon, Kenneth
AU - Thied, R.C.
PY - 2005
Y1 - 2005
N2 - The structure of the 1-alkyl-3-methylimidazolium salts of the dinuclear mu(4)-(O,O,O',O'-ethane-1,2-dioato)-bis[bis(nitrato-O,O)dioxouranate(VI)] anion have been investigated using single crystal X-ray crystallography. In addition, EXAFS and electrochemical studies have been performed on the [C(4)mim](+) salt which is formed following the oxidative dissolution of uranium(IV) oxide in [C(4)mim][NO3]. EXAFS analysis of the solution following UO2 dissolution indicates a mixture of uranyl nitrate and mu(4)-(O,O,O',O'-ethane-1,2-dioato)-bis[bis(nitrato-O,O)dioxouranate(VI)] anions are formed.
AB - The structure of the 1-alkyl-3-methylimidazolium salts of the dinuclear mu(4)-(O,O,O',O'-ethane-1,2-dioato)-bis[bis(nitrato-O,O)dioxouranate(VI)] anion have been investigated using single crystal X-ray crystallography. In addition, EXAFS and electrochemical studies have been performed on the [C(4)mim](+) salt which is formed following the oxidative dissolution of uranium(IV) oxide in [C(4)mim][NO3]. EXAFS analysis of the solution following UO2 dissolution indicates a mixture of uranyl nitrate and mu(4)-(O,O,O',O'-ethane-1,2-dioato)-bis[bis(nitrato-O,O)dioxouranate(VI)] anions are formed.
M3 - Article
VL - 901
SP - 32
EP - 46
JO - IONIC LIQUIDS IIIA: FUNDAMENTALS, PROGRESS, CHALLENGES, AND OPPORTUNITIES, PROPERTIES AND STRUCTURE
JF - IONIC LIQUIDS IIIA: FUNDAMENTALS, PROGRESS, CHALLENGES, AND OPPORTUNITIES, PROPERTIES AND STRUCTURE
ER -