Anion-templated formation of a unique inorganic 'super-adamantoid' cage [Ag-6(triphos)(4)(O3SCF3)(4)](2+) [triphos = (PPh2CH2)(3)CMe]

Stuart James, D.M.P. Mingos, A.J.P. White, D.J. Williams

Research output: Contribution to journalArticlepeer-review

Abstract

In the presence of templating anions, 2:3 molar mixtures of triphos and silver(I) cations unexpectedly give novel hexanuclear cages, which result from an unusual 'endo-methyl' geometry of the triphos ligands.
Original languageEnglish
Pages (from-to)2323-2324
Number of pages2
JournalChemical Communications
Volume1998
Publication statusPublished - 1998

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