Anion-templated formation of a unique inorganic 'super-adamantoid' cage [Ag-6(triphos)(4)(O3SCF3)(4)](2+) [triphos = (PPh2CH2)(3)CMe]

Stuart James; D.M.P. Mingos; A.J.P. White; D.J. Williams

Anion-templated formation of a unique inorganic 'super-adamantoid' cage [Ag-6(triphos)(4)(O3SCF3)(4)](2+) [triphos = (PPh2CH2)(3)CMe]

Stuart James
, D.M.P. Mingos
, A.J.P. White
, D.J. Williams

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

In the presence of templating anions, 2:3 molar mixtures of triphos and silver(I) cations unexpectedly give novel hexanuclear cages, which result from an unusual 'endo-methyl' geometry of the triphos ligands.

Original language	English
Pages (from-to)	2323-2324
Number of pages	2
Journal	Chemical Communications
Volume	1998
Publication status	Published - 1998

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@article{ae71ba3ed3424d919788bb2178c20c69,

title = "Anion-templated formation of a unique inorganic 'super-adamantoid' cage [Ag-6(triphos)(4)(O3SCF3)(4)](2+) [triphos = (PPh2CH2)(3)CMe]",

abstract = "In the presence of templating anions, 2:3 molar mixtures of triphos and silver(I) cations unexpectedly give novel hexanuclear cages, which result from an unusual 'endo-methyl' geometry of the triphos ligands.",

author = "Stuart James and D.M.P. Mingos and A.J.P. White and D.J. Williams",

year = "1998",

language = "English",

volume = "1998",

pages = "2323--2324",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry",

}

TY - JOUR

T1 - Anion-templated formation of a unique inorganic 'super-adamantoid' cage [Ag-6(triphos)(4)(O3SCF3)(4)](2+) [triphos = (PPh2CH2)(3)CMe]

AU - James, Stuart

AU - Mingos, D.M.P.

AU - White, A.J.P.

AU - Williams, D.J.

PY - 1998

Y1 - 1998

N2 - In the presence of templating anions, 2:3 molar mixtures of triphos and silver(I) cations unexpectedly give novel hexanuclear cages, which result from an unusual 'endo-methyl' geometry of the triphos ligands.

AB - In the presence of templating anions, 2:3 molar mixtures of triphos and silver(I) cations unexpectedly give novel hexanuclear cages, which result from an unusual 'endo-methyl' geometry of the triphos ligands.

M3 - Article

SN - 1359-7345

VL - 1998

SP - 2323

EP - 2324

JO - Chemical Communications

JF - Chemical Communications

ER -

Anion-templated formation of a unique inorganic 'super-adamantoid' cage [Ag-6(triphos)(4)(O3SCF3)(4)](2+) [triphos = (PPh2CH2)(3)CMe]

Abstract

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