Abstract
| Original language | English |
|---|---|
| Pages (from-to) | 247-263 |
| Number of pages | 17 |
| Journal | Faraday Discussions |
| Volume | 206 |
| Early online date | 22 May 2017 |
| DOIs | |
| Publication status | Published - 01 Jan 2018 |
Fingerprint
Cite this
}
Applying neutron diffraction with isotopic substitution to the structure and proton-transport pathways in protic imidazolium bis{(trifluoromethyl)sulfonyl}imide ionic liquids. / Turner, Adam H.; Imberti, Silvia; Swadzba-Kwasny, Malgorzata; Holbrey, John D.
In: Faraday Discussions, Vol. 206, 01.01.2018, p. 247-263.Research output: Contribution to journal › Article
TY - JOUR
T1 - Applying neutron diffraction with isotopic substitution to the structure and proton-transport pathways in protic imidazolium bis{(trifluoromethyl)sulfonyl}imide ionic liquids
AU - Turner, Adam H.
AU - Imberti, Silvia
AU - Swadzba-Kwasny, Malgorzata
AU - Holbrey, John D.
PY - 2018/1/1
Y1 - 2018/1/1
N2 - Neutron diffraction with isotopic substitution has been applied to examine the potential for complex-ion formation in protic imidazolium bis{(trifluoromethyl)sulfonyl}imide ionic liquids. Strong cation–anion hydrogen-bonding in the 1:1 base:acid ionic liquid results in a high population of anions adopting a cis-conformation and, on adding excess imidazole (2:1 base:acid stoichiometry), cation–base and base–base correlations were identified however, persistent hydrogen-bond associations were not observed.
AB - Neutron diffraction with isotopic substitution has been applied to examine the potential for complex-ion formation in protic imidazolium bis{(trifluoromethyl)sulfonyl}imide ionic liquids. Strong cation–anion hydrogen-bonding in the 1:1 base:acid ionic liquid results in a high population of anions adopting a cis-conformation and, on adding excess imidazole (2:1 base:acid stoichiometry), cation–base and base–base correlations were identified however, persistent hydrogen-bond associations were not observed.
U2 - 10.1039/c7fd00143f
DO - 10.1039/c7fd00143f
M3 - Article
VL - 206
SP - 247
EP - 263
JO - Faraday Discussions
JF - Faraday Discussions
SN - 1359-6640
ER -