Approaches to diene based homopumiliotoxin alkaloids.

H McAlonan, D Montgomery, PJ Stevenson

Research output: Contribution to journalArticle

21 Citations (Scopus)

Abstract

Palladium catalysed reductive cyclisation of a 1,1-dibromoalkene to an acetylene gives the core unit of the quinolizidine based diene homopuniliotoxin alkaloids with complete control of stereochemistry of the exocyclic double bond. Copyright (C) 1996 Elsevier Science Ltd

Original languageEnglish
Pages (from-to)7151-7154
Number of pages4
JournalTetrahedron Letters
Volume37
Issue number39
Publication statusPublished - 23 Sep 1996

Keywords

  • ENANTIOSELECTIVE TOTAL SYNTHESIS
  • PUMILIOTOXIN-A ALKALOIDS
  • CYCLIZATION
  • ACETYLENES
  • 339B

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