Atomically Thin Boron Nitride as an Ideal Spacer for Metal-Enhanced Fluorescence

Wei Gan, Christos Tserkezis, Qiran Cai, Alexey Falin, Srikanth Mateti, Minh Nguyen, Igor Aharonovich, Kenji Watanabe, Takashi Taniguchi, Fumin Huang, Li Song, Lingxue Kong, Ying Chen, Lu Hua Li

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2 Citations (Scopus)

Abstract

Metal-enhanced fluorescence (MEF) considerably enhances the luminescence for various applications, but its performance largely depends on the dielectric spacer between the fluorophore and plasmonic system. It is still challenging to produce a defect-free spacer having an optimized thickness with a sub-nanometer accuracy that enables reusability without affecting the enhancement. In this study, we demonstrate the use of atomically thin hexagonal boron nitride (BN) as an ideal MEF spacer owing to its multifold advantages over the traditional dielectric thin films. With rhodamine 6G as a representative fluorophore, it largely improves the enhancement factor (up to ∼95 ± 5), sensitivity (10-8 M), reproducibility, and reusability (∼90% of the plasmonic activity is retained after 30 cycles of heating at 350 °C in air) of MEF. This can be attributed to its two-dimensional structure, thickness control at the atomic level, defect-free quality, high affinities to aromatic fluorophores, good thermal stability, and excellent impermeability. The atomically thin BN spacers could increase the use of MEF in different fields and industries.

Original languageEnglish
Pages (from-to)12184-12191
JournalACS Nano
Volume13
Issue number10
Early online date02 Oct 2019
DOIs
Publication statusPublished - 22 Oct 2019

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    Gan, W., Tserkezis, C., Cai, Q., Falin, A., Mateti, S., Nguyen, M., Aharonovich, I., Watanabe, K., Taniguchi, T., Huang, F., Song, L., Kong, L., Chen, Y., & Li, L. H. (2019). Atomically Thin Boron Nitride as an Ideal Spacer for Metal-Enhanced Fluorescence. ACS Nano, 13(10), 12184-12191. https://doi.org/10.1021/acsnano.9b06858