Basic Ionic Liquid Gels for Catalysis: Application to the Hydrogen Borrowing Mediated Dehydration of 1,3-Propanediol.

Kyra M. Bothwell; Fabio Lorenzini; Ellen Mathers; Patricia C. Marr; Andrew C. Marr

doi:10.1021/acssuschemeng.8b05762

Basic Ionic Liquid Gels for Catalysis: Application to the Hydrogen Borrowing Mediated Dehydration of 1,3-Propanediol.

Kyra M. Bothwell, Fabio Lorenzini, Ellen Mathers, Patricia C. Marr, Andrew C. Marr

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

169 Downloads (Pure)

Abstract

The application of basic ionic liquid gels (BILGs) as recyclable promoters of hydrogen borrowing chemistry was investigated. The hydrogen transfer initiated dehydration of 1,3-propanediol to propanal was catalysed by a [Cp*IrCl2(NHC)] complex promoted by BILGs containing [P6,6,6,14][OH]. Gels comprising a mixture of basic and hydrophobic ionic liquids gave the best results. The reaction proceeded in the ionic liquid [C2mmim][NTf2] enabling the continuous removal of propanal under reduced pressure. Tuning of the composition of the BILG led to a catalytic system that exhibited excellent conversion, selectivity and good recyclability.

Original language	English
Pages (from-to)	2686–2690
Journal	ACS Sustainable Chemistry & Engineering
Volume	7
Issue number	2
Early online date	24 Dec 2018
DOIs	https://doi.org/10.1021/acssuschemeng.8b05762
Publication status	Published - 22 Jan 2019

Access to Document

10.1021/acssuschemeng.8b05762Licence: Unspecified

Basic Ionic Liquid Gels for Catalysis: Application to the Hydrogen Borrowing Mediated Dehydration of 1,3-Propanediol.
Copyright © 2018 American Chemical Society. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 593 KBLicence: Unspecified

Andrew Marr
- a.marrqub.acuk
- School of Chemistry and Chemical Engineering - Senior Lecturer
Person: Academic

Cite this

@article{7f40d19c6c5f4b96a0b3a0049c8a392a,

title = "Basic Ionic Liquid Gels for Catalysis: Application to the Hydrogen Borrowing Mediated Dehydration of 1,3-Propanediol.",

abstract = "The application of basic ionic liquid gels (BILGs) as recyclable promoters of hydrogen borrowing chemistry was investigated. The hydrogen transfer initiated dehydration of 1,3-propanediol to propanal was catalysed by a [Cp*IrCl2(NHC)] complex promoted by BILGs containing [P6,6,6,14][OH]. Gels comprising a mixture of basic and hydrophobic ionic liquids gave the best results. The reaction proceeded in the ionic liquid [C2mmim][NTf2] enabling the continuous removal of propanal under reduced pressure. Tuning of the composition of the BILG led to a catalytic system that exhibited excellent conversion, selectivity and good recyclability. ",

author = "Bothwell, {Kyra M.} and Fabio Lorenzini and Ellen Mathers and Marr, {Patricia C.} and Marr, {Andrew C.}",

year = "2019",

month = jan,

day = "22",

doi = "10.1021/acssuschemeng.8b05762",

language = "English",

volume = "7",

pages = "2686–2690",

journal = "ACS Sustainable Chemistry & Engineering",

issn = "2168-0485",

publisher = "American Chemical Society",

number = "2",

}

TY - JOUR

T1 - Basic Ionic Liquid Gels for Catalysis: Application to the Hydrogen Borrowing Mediated Dehydration of 1,3-Propanediol.

AU - Bothwell, Kyra M.

AU - Lorenzini, Fabio

AU - Mathers, Ellen

AU - Marr, Patricia C.

AU - Marr, Andrew C.

PY - 2019/1/22

Y1 - 2019/1/22

N2 - The application of basic ionic liquid gels (BILGs) as recyclable promoters of hydrogen borrowing chemistry was investigated. The hydrogen transfer initiated dehydration of 1,3-propanediol to propanal was catalysed by a [Cp*IrCl2(NHC)] complex promoted by BILGs containing [P6,6,6,14][OH]. Gels comprising a mixture of basic and hydrophobic ionic liquids gave the best results. The reaction proceeded in the ionic liquid [C2mmim][NTf2] enabling the continuous removal of propanal under reduced pressure. Tuning of the composition of the BILG led to a catalytic system that exhibited excellent conversion, selectivity and good recyclability.

AB - The application of basic ionic liquid gels (BILGs) as recyclable promoters of hydrogen borrowing chemistry was investigated. The hydrogen transfer initiated dehydration of 1,3-propanediol to propanal was catalysed by a [Cp*IrCl2(NHC)] complex promoted by BILGs containing [P6,6,6,14][OH]. Gels comprising a mixture of basic and hydrophobic ionic liquids gave the best results. The reaction proceeded in the ionic liquid [C2mmim][NTf2] enabling the continuous removal of propanal under reduced pressure. Tuning of the composition of the BILG led to a catalytic system that exhibited excellent conversion, selectivity and good recyclability.

U2 - 10.1021/acssuschemeng.8b05762

DO - 10.1021/acssuschemeng.8b05762

M3 - Article

VL - 7

SP - 2686

EP - 2690

JO - ACS Sustainable Chemistry & Engineering

JF - ACS Sustainable Chemistry & Engineering

SN - 2168-0485

IS - 2

ER -

Basic Ionic Liquid Gels for Catalysis: Application to the Hydrogen Borrowing Mediated Dehydration of 1,3-Propanediol.

Abstract

Access to Document

Fingerprint

Profiles

Andrew Marr

Cite this