Bronsted-Evans-Polanyi relation of multistep reactions and volcano curve in heterogeneous catalysis

J. Cheng; Peijun Hu; P. Ellis; S. French; G. Kelly; C.M. Lok

doi:10.1021/jp711191j

Bronsted-Evans-Polanyi relation of multistep reactions and volcano curve in heterogeneous catalysis

J. Cheng, Peijun Hu, P. Ellis, S. French, G. Kelly, C.M. Lok

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

129 Citations (Scopus)

Abstract

Multistep surface processes involving a number of association reactions and desorption processes may be considered as hypothetical one-step desorption processes. Thus, heterogeneous catalytic reactions can be treated kinetically as consisting of two steps: adsorption and desorption. It is also illustrated that the hypothetical one-step desorption process follows the BEP relation. A volcano curve can be obtained from kinetic analysis by including both adsorption and desorption processes.

Original language	English
Pages (from-to)	1308-1311
Number of pages	4
Journal	Journal of Physical Chemistry C
Volume	112 (5)
Issue number	5
DOIs	https://doi.org/10.1021/jp711191j
Publication status	Published - 07 Jan 2008

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Electronic, Optical and Magnetic Materials
Surfaces, Coatings and Films
Energy(all)

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10.1021/jp711191j

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abstract = "Multistep surface processes involving a number of association reactions and desorption processes may be considered as hypothetical one-step desorption processes. Thus, heterogeneous catalytic reactions can be treated kinetically as consisting of two steps: adsorption and desorption. It is also illustrated that the hypothetical one-step desorption process follows the BEP relation. A volcano curve can be obtained from kinetic analysis by including both adsorption and desorption processes.",

author = "J. Cheng and Peijun Hu and P. Ellis and S. French and G. Kelly and C.M. Lok",

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AU - Cheng, J.

AU - Hu, Peijun

AU - Ellis, P.

AU - French, S.

AU - Kelly, G.

AU - Lok, C.M.

PY - 2008/1/7

Y1 - 2008/1/7

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AB - Multistep surface processes involving a number of association reactions and desorption processes may be considered as hypothetical one-step desorption processes. Thus, heterogeneous catalytic reactions can be treated kinetically as consisting of two steps: adsorption and desorption. It is also illustrated that the hypothetical one-step desorption process follows the BEP relation. A volcano curve can be obtained from kinetic analysis by including both adsorption and desorption processes.

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JF - The Journal of Physical Chemistry C

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Bronsted-Evans-Polanyi relation of multistep reactions and volcano curve in heterogeneous catalysis

Abstract

ASJC Scopus subject areas

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