Calcium-bearing cyanopolyynes in IRC+10216

In recent years, a number of metal-containing, carbon-chain species have been detected in the external circumstellar envelope of the carbon-rich AGB star IRC+10216. The most common metal detected in such species is Mg, for which molecules as large as MgC₅N, MgC₅N⁺, MgC₆H and MgC₆H⁺ have been observed. In this paper, we calculate the likely abundances of the Ca bearing cyanopolyynes, CaC_2n+1N for n = 1-4, drawing the conclusion that the observed abundance of CaNC must be made from much larger Ca-terminated cyanopolyyne ions, which requires considerable rearrangement in their dissociative recombination. We pay particular attention to the detectability of CaC₃N whose rotational spectrum has recently been measured.