Catalytic depolymerisation of suberin rich biomass with precious metal catalysts

Christopher S McCallum; Nicholas  Strachan; Stephen C Bennett; W. Graham Forsythe; Mark D Garrett; Christopher Hardacre; Kevin Morgan; Gary N. Sheldrake

doi:10.1039/C8GC00605A

Catalytic depolymerisation of suberin rich biomass with precious metal catalysts

Christopher S McCallum, Nicholas Strachan, Stephen C Bennett, W. Graham Forsythe, Mark D Garrett, Christopher Hardacre, Kevin Morgan, Gary N. Sheldrake

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Abstract

Hydrogenolysis of cork has been examined using a range of precious metal catalysts studying the effect of the support, added base and solvent used. The addition of a catalyst and a base resulted in a bio-oil increase of 9.3 – 158 % compared to when no catalyst was used along with an increase in lipid yield of 113-258 %. The solvent change to 2-methyl tetrahydrofuran from the original dioxane solvent system allowed for a change to a “greener” solvent as well as an increased yield from 11.5 wt% bio-oil yield to 42.6 wt% bio-oil yield, in the absence of base

Original language	English
Pages (from-to)	2702-2705
Journal	Green Chemistry
Volume	20
Issue number	12
Early online date	01 May 2018
DOIs	https://doi.org/10.1039/C8GC00605A
Publication status	Published - 21 Jun 2018

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Catalytic depolymerisation of suberin rich biomass with precious metal catalysts
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title = "Catalytic depolymerisation of suberin rich biomass with precious metal catalysts",

abstract = "Hydrogenolysis of cork has been examined using a range of precious metal catalysts studying the effect of the support, added base and solvent used. The addition of a catalyst and a base resulted in a bio-oil increase of 9.3 – 158 % compared to when no catalyst was used along with an increase in lipid yield of 113-258 %. The solvent change to 2-methyl tetrahydrofuran from the original dioxane solvent system allowed for a change to a “greener” solvent as well as an increased yield from 11.5 wt% bio-oil yield to 42.6 wt% bio-oil yield, in the absence of base",

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AU - McCallum, Christopher S

AU - Strachan, Nicholas

AU - Bennett, Stephen C

AU - Forsythe, W. Graham

AU - Garrett, Mark D

AU - Hardacre, Christopher

AU - Morgan, Kevin

AU - Sheldrake, Gary N.

PY - 2018/6/21

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N2 - Hydrogenolysis of cork has been examined using a range of precious metal catalysts studying the effect of the support, added base and solvent used. The addition of a catalyst and a base resulted in a bio-oil increase of 9.3 – 158 % compared to when no catalyst was used along with an increase in lipid yield of 113-258 %. The solvent change to 2-methyl tetrahydrofuran from the original dioxane solvent system allowed for a change to a “greener” solvent as well as an increased yield from 11.5 wt% bio-oil yield to 42.6 wt% bio-oil yield, in the absence of base

AB - Hydrogenolysis of cork has been examined using a range of precious metal catalysts studying the effect of the support, added base and solvent used. The addition of a catalyst and a base resulted in a bio-oil increase of 9.3 – 158 % compared to when no catalyst was used along with an increase in lipid yield of 113-258 %. The solvent change to 2-methyl tetrahydrofuran from the original dioxane solvent system allowed for a change to a “greener” solvent as well as an increased yield from 11.5 wt% bio-oil yield to 42.6 wt% bio-oil yield, in the absence of base

U2 - 10.1039/C8GC00605A

DO - 10.1039/C8GC00605A

M3 - Article

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SN - 1463-9262

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