Catalytic depolymerisation of suberin rich biomass with precious metal catalysts

Christopher S McCallum; Nicholas  Strachan; Stephen C Bennett; W. Graham Forsythe; Mark D Garrett; Christopher Hardacre; Kevin Morgan; Gary N. Sheldrake

doi:10.1039/C8GC00605A

Catalytic depolymerisation of suberin rich biomass with precious metal catalysts

Christopher S McCallum
, Nicholas Strachan
, Stephen C Bennett
, W. Graham Forsythe
, Mark D Garrett
, Christopher Hardacre
, Kevin Morgan
, Gary N. Sheldrake

Research output: Contribution to journal › Article › peer-review

21 Citations (Scopus)

282 Downloads (Pure)

Abstract

Hydrogenolysis of cork has been examined using a range of precious metal catalysts studying the effect of the support, added base and solvent used. The addition of a catalyst and a base resulted in a bio-oil increase of 9.3 – 158 % compared to when no catalyst was used along with an increase in lipid yield of 113-258 %. The solvent change to 2-methyl tetrahydrofuran from the original dioxane solvent system allowed for a change to a “greener” solvent as well as an increased yield from 11.5 wt% bio-oil yield to 42.6 wt% bio-oil yield, in the absence of base

Original language	English
Pages (from-to)	2702-2705
Journal	Green Chemistry
Volume	20
Issue number	12
Early online date	01 May 2018
DOIs	https://doi.org/10.1039/C8GC00605A
Publication status	Published - 21 Jun 2018

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This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy
SDG 12 Responsible Consumption and Production

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10.1039/C8GC00605ALicence: Unspecified

Catalytic depolymerisation of suberin rich biomass with precious metal catalysts
Copyright 2018 Royal Society of Chemistry. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 472 KBLicence: Unspecified

Gary Sheldrake
- g.sheldrakequb.acuk
- School of Chemistry and Chemical Engineering - Visiting Scholar
- Green and Sustainable Chemistry
Person: Academic

Cite this

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title = "Catalytic depolymerisation of suberin rich biomass with precious metal catalysts",

abstract = "Hydrogenolysis of cork has been examined using a range of precious metal catalysts studying the effect of the support, added base and solvent used. The addition of a catalyst and a base resulted in a bio-oil increase of 9.3 {\textendash} 158 \% compared to when no catalyst was used along with an increase in lipid yield of 113-258 \%. The solvent change to 2-methyl tetrahydrofuran from the original dioxane solvent system allowed for a change to a {\textquotedblleft}greener{\textquotedblright} solvent as well as an increased yield from 11.5 wt\% bio-oil yield to 42.6 wt\% bio-oil yield, in the absence of base",

author = "McCallum, \{Christopher S\} and Nicholas Strachan and Bennett, \{Stephen C\} and Forsythe, \{W. Graham\} and Garrett, \{Mark D\} and Christopher Hardacre and Kevin Morgan and Sheldrake, \{Gary N.\}",

year = "2018",

month = jun,

day = "21",

doi = "10.1039/C8GC00605A",

language = "English",

volume = "20",

pages = "2702--2705",

journal = "Green Chemistry",

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T1 - Catalytic depolymerisation of suberin rich biomass with precious metal catalysts

AU - McCallum, Christopher S

AU - Strachan, Nicholas

AU - Bennett, Stephen C

AU - Forsythe, W. Graham

AU - Garrett, Mark D

AU - Hardacre, Christopher

AU - Morgan, Kevin

AU - Sheldrake, Gary N.

PY - 2018/6/21

Y1 - 2018/6/21

N2 - Hydrogenolysis of cork has been examined using a range of precious metal catalysts studying the effect of the support, added base and solvent used. The addition of a catalyst and a base resulted in a bio-oil increase of 9.3 – 158 % compared to when no catalyst was used along with an increase in lipid yield of 113-258 %. The solvent change to 2-methyl tetrahydrofuran from the original dioxane solvent system allowed for a change to a “greener” solvent as well as an increased yield from 11.5 wt% bio-oil yield to 42.6 wt% bio-oil yield, in the absence of base

AB - Hydrogenolysis of cork has been examined using a range of precious metal catalysts studying the effect of the support, added base and solvent used. The addition of a catalyst and a base resulted in a bio-oil increase of 9.3 – 158 % compared to when no catalyst was used along with an increase in lipid yield of 113-258 %. The solvent change to 2-methyl tetrahydrofuran from the original dioxane solvent system allowed for a change to a “greener” solvent as well as an increased yield from 11.5 wt% bio-oil yield to 42.6 wt% bio-oil yield, in the absence of base

U2 - 10.1039/C8GC00605A

DO - 10.1039/C8GC00605A

M3 - Article

SN - 1463-9262

VL - 20

SP - 2702

EP - 2705

JO - Green Chemistry

JF - Green Chemistry

IS - 12

ER -

Catalytic depolymerisation of suberin rich biomass with precious metal catalysts

Abstract

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