Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts

A.R. Dubrovskii; S.A. Kuznetsov; Evgeny Rebrov; J.C. Schouten

doi:10.1134/S0023158408040216

Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts

A.R. Dubrovskii, S.A. Kuznetsov, Evgeny Rebrov, J.C. Schouten

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

8 Citations (Scopus)

Abstract

Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO42 and CO32- are catalytically more active than bulk Mo2C or the commercial catalyst Cu-ZnO-Al2O3 by one and three orders of magnitude, respectively.

Original language	English
Pages (from-to)	594-598
Number of pages	5
Journal	Kinetics and Catalysis
Volume	49
Issue number	4
DOIs	https://doi.org/10.1134/S0023158408040216
Publication status	Published - Jul 2008

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

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abstract = "Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO42 and CO32- are catalytically more active than bulk Mo2C or the commercial catalyst Cu-ZnO-Al2O3 by one and three orders of magnitude, respectively.",

author = "A.R. Dubrovskii and S.A. Kuznetsov and Evgeny Rebrov and J.C. Schouten",

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AU - Dubrovskii, A.R.

AU - Kuznetsov, S.A.

AU - Rebrov, Evgeny

AU - Schouten, J.C.

PY - 2008/7

Y1 - 2008/7

N2 - Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO42 and CO32- are catalytically more active than bulk Mo2C or the commercial catalyst Cu-ZnO-Al2O3 by one and three orders of magnitude, respectively.

AB - Electrosynthesis methods using molten salts are suggested for obtaining a new catalytic system based on the Mo2C/Mo composition for the water gas shift reaction. The coatings obtained by the discharge of the carbonate ion on a molybdenum substrate and by the simultaneous reduction of the electroactive species MoO42 and CO32- are catalytically more active than bulk Mo2C or the commercial catalyst Cu-ZnO-Al2O3 by one and three orders of magnitude, respectively.

U2 - 10.1134/S0023158408040216

DO - 10.1134/S0023158408040216

M3 - Article

SN - 1608-3210

VL - 49

SP - 594

EP - 598

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

IS - 4

ER -

Catalytic Mo2C coatings for the water gas shift reaction: Electrosynthesis in molten salts

Abstract

ASJC Scopus subject areas

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