Cationic palladium(II) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide.

Qun Cao; David S Bailie; Runzhong Fu; Mark J Muldoon

doi:10.1039/C4GC02465F

Cationic palladium(II) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide.

Qun Cao, David S Bailie, Runzhong Fu, Mark J Muldoon

School of Chemistry and Chemical Engineering

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Abstract

Ligated Pd(II) complexes have been studied for the catalytic oxidation of terminal olefins to their corresponding methyl ketones. The method uses aqueous hydrogen peroxide as the terminal oxidant; a sustainable and readily accessible oxidant. The choice of ligand, counterion and solvent all have a significant effect on catalytic performance and we were able to develop systems which perform well for these challenging oxidations.

Original language	English
Pages (from-to)	2750-2757
Number of pages	8
Journal	Green Chemistry
Volume	17
Early online date	09 Mar 2015
DOIs	https://doi.org/10.1039/C4GC02465F
Publication status	Published - May 2015

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10.1039/C4GC02465F

Cationic palladium(II) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide
This journal is © The Royal Society of Chemistry 2015. This article is licensed under a Creative Commons Attribution 3.0 Unported Licence, which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
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Mark Muldoon
- m.j.muldoonqub.acuk
- School of Chemistry and Chemical Engineering - Deputy Head of School
- Research Centre in Sustainable Energy
- Green and Sustainable Chemistry
Person: Academic

Cite this

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title = "Cationic palladium(II) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide.",

abstract = "Ligated Pd(II) complexes have been studied for the catalytic oxidation of terminal olefins to their corresponding methyl ketones. The method uses aqueous hydrogen peroxide as the terminal oxidant; a sustainable and readily accessible oxidant. The choice of ligand, counterion and solvent all have a significant effect on catalytic performance and we were able to develop systems which perform well for these challenging oxidations.",

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AU - Bailie, David S

AU - Fu, Runzhong

AU - Muldoon, Mark J

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AB - Ligated Pd(II) complexes have been studied for the catalytic oxidation of terminal olefins to their corresponding methyl ketones. The method uses aqueous hydrogen peroxide as the terminal oxidant; a sustainable and readily accessible oxidant. The choice of ligand, counterion and solvent all have a significant effect on catalytic performance and we were able to develop systems which perform well for these challenging oxidations.

U2 - 10.1039/C4GC02465F

DO - 10.1039/C4GC02465F

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SN - 1463-9262

ER -

Cationic palladium(II) complexes as catalysts for the oxidation of terminal olefins to methyl ketones using hydrogen peroxide.

Abstract

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Mark Muldoon

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