Chain confinement promotes β-phase formation in polyfluorene-based photoluminescent ionogels

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Abstract

The synthesis of photoluminescent conjugated polymer silica ionogels using sol–gel chemistry is described. Cooperative self-assembly of an ionic liquid, the silica precursor and poly(9,9-dioctylfluorene) (PFO) via hydrogen bonding and p-stacking interactions drives formation of the PFO ß-phase.
Original languageEnglish
Pages (from-to)3742-3744
Number of pages3
JournalChemical Communications
Volume48
Issue number31
DOIs
Publication statusPublished - 2012

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