TY - JOUR
T1 - Characterisation of Robust Combustion Catalyst from Aluminium Foil Waste
AU - Osman , Ahmed I.
AU - Abu-Dahrieh, Jehad K.
AU - McLaren, Mathew
AU - Laffir, Fathima
AU - Rooney, David W.
PY - 2018/2/6
Y1 - 2018/2/6
N2 - Herein a robust and active combustion catalyst was prepared with three-quarter (75 wt.%) of its composition derived from the aluminium foil waste and designated as 5Pd-ACFL. The prepared catalyst was characterised using X-ray diffraction (XRD), Temperature-programmed reduction (TPR), Bright-field transmission electron microscopy (BF-TEM), High angle annular dark field (HAADF), Fourier transform infrared-pyridine (FTIR-Pyridine) and X-ray Photoelectron Spectroscopy (XPS) techniques and compared to the commercial equivalent (5Pd-AC550). The catalyst 5Pd-ACFL550 showed higher catalytic activity than that of 5Pd-AC550 in the total methane oxidation reaction with T50% at 303 ºC at Gas hourly space velocity (GHSV) of 100,000 mL g-1 h-1. Our approach opens doors for the preparation of robust cheap combustion catalyst from aluminium foil waste and demonstrates its application in the catalytic converters of natural gas vehicles (NGV-vehicles) and other combustion applications. As a result, this can be opened up to a wider variety of application markets, including residential and automotive applications.
AB - Herein a robust and active combustion catalyst was prepared with three-quarter (75 wt.%) of its composition derived from the aluminium foil waste and designated as 5Pd-ACFL. The prepared catalyst was characterised using X-ray diffraction (XRD), Temperature-programmed reduction (TPR), Bright-field transmission electron microscopy (BF-TEM), High angle annular dark field (HAADF), Fourier transform infrared-pyridine (FTIR-Pyridine) and X-ray Photoelectron Spectroscopy (XPS) techniques and compared to the commercial equivalent (5Pd-AC550). The catalyst 5Pd-ACFL550 showed higher catalytic activity than that of 5Pd-AC550 in the total methane oxidation reaction with T50% at 303 ºC at Gas hourly space velocity (GHSV) of 100,000 mL g-1 h-1. Our approach opens doors for the preparation of robust cheap combustion catalyst from aluminium foil waste and demonstrates its application in the catalytic converters of natural gas vehicles (NGV-vehicles) and other combustion applications. As a result, this can be opened up to a wider variety of application markets, including residential and automotive applications.
U2 - 10.1002/slct.201702660
DO - 10.1002/slct.201702660
M3 - Article
SN - 2365-6549
JO - ChemistrySelect
JF - ChemistrySelect
ER -