Chemical control through dissociative electron attachment - A study on pentafluorotoluene, pentafluoroaniline and pentafluorophenol

Benedikt Omarsson; Elias H. Bjarnason; Oddur Ingolfsson; Sean Haughey; Thomas A. Field

doi:10.1016/j.cplett.2012.04.059

Chemical control through dissociative electron attachment - A study on pentafluorotoluene, pentafluoroaniline and pentafluorophenol

Benedikt Omarsson, Elias H. Bjarnason, Oddur Ingolfsson, Sean Haughey, Thomas A. Field

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Abstract

In a combined experimental and theoretical study on dissociative electron attachment (DEA) to pentafluorotoluene, pentafluoroaniline and pentafluorophenol in the energy range 0-3 eV we reveal the role of rearrangement and hydrogen bonded intermediates in the DEA process and show that HF formation can be used to enable otherwise inaccessible, efficient low energy DEA processes.

Original language	English
Pages (from-to)	7-10
Number of pages	4
Journal	Chemical Physics Letters
Volume	539
DOIs	https://doi.org/10.1016/j.cplett.2012.04.059
Publication status	Published - 29 Jun 2012

ASJC Scopus subject areas

Physical and Theoretical Chemistry
General Physics and Astronomy

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10.1016/j.cplett.2012.04.059

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title = "Chemical control through dissociative electron attachment - A study on pentafluorotoluene, pentafluoroaniline and pentafluorophenol",

abstract = "In a combined experimental and theoretical study on dissociative electron attachment (DEA) to pentafluorotoluene, pentafluoroaniline and pentafluorophenol in the energy range 0-3 eV we reveal the role of rearrangement and hydrogen bonded intermediates in the DEA process and show that HF formation can be used to enable otherwise inaccessible, efficient low energy DEA processes.",

author = "Benedikt Omarsson and Bjarnason, {Elias H.} and Oddur Ingolfsson and Sean Haughey and Field, {Thomas A.}",

year = "2012",

month = jun,

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doi = "10.1016/j.cplett.2012.04.059",

language = "English",

volume = "539",

pages = "7--10",

journal = "Chemical Physics Letters",

issn = "0009-2614",

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T1 - Chemical control through dissociative electron attachment - A study on pentafluorotoluene, pentafluoroaniline and pentafluorophenol

AU - Omarsson, Benedikt

AU - Bjarnason, Elias H.

AU - Ingolfsson, Oddur

AU - Haughey, Sean

AU - Field, Thomas A.

PY - 2012/6/29

Y1 - 2012/6/29

N2 - In a combined experimental and theoretical study on dissociative electron attachment (DEA) to pentafluorotoluene, pentafluoroaniline and pentafluorophenol in the energy range 0-3 eV we reveal the role of rearrangement and hydrogen bonded intermediates in the DEA process and show that HF formation can be used to enable otherwise inaccessible, efficient low energy DEA processes.

AB - In a combined experimental and theoretical study on dissociative electron attachment (DEA) to pentafluorotoluene, pentafluoroaniline and pentafluorophenol in the energy range 0-3 eV we reveal the role of rearrangement and hydrogen bonded intermediates in the DEA process and show that HF formation can be used to enable otherwise inaccessible, efficient low energy DEA processes.

U2 - 10.1016/j.cplett.2012.04.059

DO - 10.1016/j.cplett.2012.04.059

M3 - Article

SN - 0009-2614

VL - 539

SP - 7

EP - 10

JO - Chemical Physics Letters

JF - Chemical Physics Letters

ER -

Chemical control through dissociative electron attachment - A study on pentafluorotoluene, pentafluoroaniline and pentafluorophenol

Abstract

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