Chemoenzymatic synthesis of chiral 4,4 '-bipyridyls and their metal-organic frameworks

Lenuta Sbircea; Narain Sharma; W. Clegg; R.W. Harrington; Patricia Horton; M.B. Hursthouse; D.C. Apperley; Derek Boyd; Stuart James

doi:10.1039/b812366g

Chemoenzymatic synthesis of chiral 4,4 '-bipyridyls and their metal-organic frameworks

Lenuta Sbircea, Narain Sharma, W. Clegg, R.W. Harrington, Patricia Horton, M.B. Hursthouse, D.C. Apperley, Derek Boyd, Stuart James

Research output: Contribution to journal › Article › peer-review

41 Citations (Scopus)

Abstract

The first enantiopure 4,4'-bipyridyls, 6, 8, and 9 have been prepared in four or five steps via bacterial dioxygenase-catalysed cis-dihydroxylation of 4-chloroquinoline 1 and C-C coupling; ligands 6 and 9 are found to be effective building blocks for the preparation of chiral metal-organic frameworks as demonstrated with the rational synthesis of two pillared-grid structures [Zn-2(fumarate)(2)(L)], which exhibit interesting structural and dynamic aspects.

Original language	English
Pages (from-to)	5538-5540
Number of pages	3
Journal	Chemical Communications
Volume	1
Issue number	43
DOIs	https://doi.org/10.1039/b812366g
Publication status	Published - 2008

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Ceramics and Composites
Electronic, Optical and Magnetic Materials
Materials Chemistry
Metals and Alloys
Surfaces, Coatings and Films

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title = "Chemoenzymatic synthesis of chiral 4,4 '-bipyridyls and their metal-organic frameworks",

abstract = "The first enantiopure 4,4'-bipyridyls, 6, 8, and 9 have been prepared in four or five steps via bacterial dioxygenase-catalysed cis-dihydroxylation of 4-chloroquinoline 1 and C-C coupling; ligands 6 and 9 are found to be effective building blocks for the preparation of chiral metal-organic frameworks as demonstrated with the rational synthesis of two pillared-grid structures [Zn-2(fumarate)(2)(L)], which exhibit interesting structural and dynamic aspects.",

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T1 - Chemoenzymatic synthesis of chiral 4,4 '-bipyridyls and their metal-organic frameworks

AU - Sbircea, Lenuta

AU - Sharma, Narain

AU - Clegg, W.

AU - Harrington, R.W.

AU - Horton, Patricia

AU - Hursthouse, M.B.

AU - Apperley, D.C.

AU - Boyd, Derek

AU - James, Stuart

PY - 2008

Y1 - 2008

N2 - The first enantiopure 4,4'-bipyridyls, 6, 8, and 9 have been prepared in four or five steps via bacterial dioxygenase-catalysed cis-dihydroxylation of 4-chloroquinoline 1 and C-C coupling; ligands 6 and 9 are found to be effective building blocks for the preparation of chiral metal-organic frameworks as demonstrated with the rational synthesis of two pillared-grid structures [Zn-2(fumarate)(2)(L)], which exhibit interesting structural and dynamic aspects.

AB - The first enantiopure 4,4'-bipyridyls, 6, 8, and 9 have been prepared in four or five steps via bacterial dioxygenase-catalysed cis-dihydroxylation of 4-chloroquinoline 1 and C-C coupling; ligands 6 and 9 are found to be effective building blocks for the preparation of chiral metal-organic frameworks as demonstrated with the rational synthesis of two pillared-grid structures [Zn-2(fumarate)(2)(L)], which exhibit interesting structural and dynamic aspects.

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U2 - 10.1039/b812366g

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JF - Chemical Communications

SN - 1359-7345

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