Comment on the preparation of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate: a unique monomeric, homoleptic pentacoordinate lead ethanoate complex

J.T. Hamill, Christopher Hardacre, Mark Nieuwenhuyzen, Kenneth Seddon, Sarah Thompson, B. Ellis

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

Atomic absorption spectroscopy of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate ([emim](2)[O2CMe]), prepared according to International Patent WO 96/18459, showed it to contain large amounts of lead impurity: (ca. 0.5 M): [emim](2)[Pb(O2CMe)(4)] was isolated and shown crystallographically to contain the first known example of a monomeric, homoleptic pentacoordinate lead(ii) carboxylate complex, with a stereochemically active lone-pair.
Original languageEnglish
Pages (from-to)1929-1930
Number of pages2
JournalChemical Communications
Issue number19
Publication statusPublished - 07 Oct 2000

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Ionic Liquids
Ionic liquids
Lead
Atomic spectroscopy
Absorption spectroscopy
Impurities
1-ethyl-3-methylimidazolium

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Hamill, J.T. ; Hardacre, Christopher ; Nieuwenhuyzen, Mark ; Seddon, Kenneth ; Thompson, Sarah ; Ellis, B. / Comment on the preparation of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate: a unique monomeric, homoleptic pentacoordinate lead ethanoate complex. In: Chemical Communications. 2000 ; No. 19. pp. 1929-1930.
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abstract = "Atomic absorption spectroscopy of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate ([emim](2)[O2CMe]), prepared according to International Patent WO 96/18459, showed it to contain large amounts of lead impurity: (ca. 0.5 M): [emim](2)[Pb(O2CMe)(4)] was isolated and shown crystallographically to contain the first known example of a monomeric, homoleptic pentacoordinate lead(ii) carboxylate complex, with a stereochemically active lone-pair.",
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Comment on the preparation of the ionic liquid 1-ethyl-3-methylimidazolium ethanoate: a unique monomeric, homoleptic pentacoordinate lead ethanoate complex. / Hamill, J.T.; Hardacre, Christopher; Nieuwenhuyzen, Mark; Seddon, Kenneth; Thompson, Sarah; Ellis, B.

In: Chemical Communications, No. 19, 07.10.2000, p. 1929-1930.

Research output: Contribution to journalArticle

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