Controlled chemistry of Moisture Sensitive Reagents in Ionic Liquids

E. J. Amigues, C. Hardacre, G. Keane, M. E. Migaud, S. E. Norman, W. R. Pitner

Research output: Chapter in Book/Report/Conference proceedingConference contribution

1 Citation (Scopus)

Abstract

Many reactions involving phosphorus reagents require highly anhydrous and inert conditions for their successful implementation. In particular, the use of PCl3 and its derivatives for synthesis is often hampered by the inherent sensitivity of the materials themselves. Ionic liquids are emerging as green alternative solvents for a range of processes, and in particular have proven to be excellent media for highly sensitive phosphorus reagents without the need for anhydrous or inert conditions. Herein, we report the use of ionic liquids as both storage and reaction media which allows difficult and sensitive chemistry to be achieved in a more accessible manner.

Original languageEnglish
Title of host publicationMOLTEN SALTS AND IONIC LIQUIDS 17
EditorsDM Fox, M Mizuhata, HC DeLong, RA Mantz, PC Trulove
Place of PublicationPENNINGTON
PublisherELECTROCHEMICAL SOC INC
Pages63-72
Number of pages10
ISBN (Print)978-1-60768-176-2
DOIs
Publication statusPublished - 2010
Event17th International Symposium on Molten Salts and Ionic Liquids as Part of the 218th Meeting of the Electrochemical-Society - Las Vegas, United States
Duration: 10 Oct 201015 Oct 2010

Conference

Conference17th International Symposium on Molten Salts and Ionic Liquids as Part of the 218th Meeting of the Electrochemical-Society
CountryUnited States
CityLas Vegas
Period10/10/201015/10/2010

Cite this

Amigues, E. J., Hardacre, C., Keane, G., Migaud, M. E., Norman, S. E., & Pitner, W. R. (2010). Controlled chemistry of Moisture Sensitive Reagents in Ionic Liquids. In DM. Fox, M. Mizuhata, HC. DeLong, RA. Mantz, & PC. Trulove (Eds.), MOLTEN SALTS AND IONIC LIQUIDS 17 (pp. 63-72). PENNINGTON: ELECTROCHEMICAL SOC INC. https://doi.org/10.1149/1.3484762
Amigues, E. J. ; Hardacre, C. ; Keane, G. ; Migaud, M. E. ; Norman, S. E. ; Pitner, W. R. / Controlled chemistry of Moisture Sensitive Reagents in Ionic Liquids. MOLTEN SALTS AND IONIC LIQUIDS 17. editor / DM Fox ; M Mizuhata ; HC DeLong ; RA Mantz ; PC Trulove. PENNINGTON : ELECTROCHEMICAL SOC INC, 2010. pp. 63-72
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abstract = "Many reactions involving phosphorus reagents require highly anhydrous and inert conditions for their successful implementation. In particular, the use of PCl3 and its derivatives for synthesis is often hampered by the inherent sensitivity of the materials themselves. Ionic liquids are emerging as green alternative solvents for a range of processes, and in particular have proven to be excellent media for highly sensitive phosphorus reagents without the need for anhydrous or inert conditions. Herein, we report the use of ionic liquids as both storage and reaction media which allows difficult and sensitive chemistry to be achieved in a more accessible manner.",
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Amigues, EJ, Hardacre, C, Keane, G, Migaud, ME, Norman, SE & Pitner, WR 2010, Controlled chemistry of Moisture Sensitive Reagents in Ionic Liquids. in DM Fox, M Mizuhata, HC DeLong, RA Mantz & PC Trulove (eds), MOLTEN SALTS AND IONIC LIQUIDS 17. ELECTROCHEMICAL SOC INC, PENNINGTON, pp. 63-72, 17th International Symposium on Molten Salts and Ionic Liquids as Part of the 218th Meeting of the Electrochemical-Society, Las Vegas, United States, 10/10/2010. https://doi.org/10.1149/1.3484762

Controlled chemistry of Moisture Sensitive Reagents in Ionic Liquids. / Amigues, E. J.; Hardacre, C.; Keane, G.; Migaud, M. E.; Norman, S. E.; Pitner, W. R.

MOLTEN SALTS AND IONIC LIQUIDS 17. ed. / DM Fox; M Mizuhata; HC DeLong; RA Mantz; PC Trulove. PENNINGTON : ELECTROCHEMICAL SOC INC, 2010. p. 63-72.

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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T1 - Controlled chemistry of Moisture Sensitive Reagents in Ionic Liquids

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AU - Pitner, W. R.

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N2 - Many reactions involving phosphorus reagents require highly anhydrous and inert conditions for their successful implementation. In particular, the use of PCl3 and its derivatives for synthesis is often hampered by the inherent sensitivity of the materials themselves. Ionic liquids are emerging as green alternative solvents for a range of processes, and in particular have proven to be excellent media for highly sensitive phosphorus reagents without the need for anhydrous or inert conditions. Herein, we report the use of ionic liquids as both storage and reaction media which allows difficult and sensitive chemistry to be achieved in a more accessible manner.

AB - Many reactions involving phosphorus reagents require highly anhydrous and inert conditions for their successful implementation. In particular, the use of PCl3 and its derivatives for synthesis is often hampered by the inherent sensitivity of the materials themselves. Ionic liquids are emerging as green alternative solvents for a range of processes, and in particular have proven to be excellent media for highly sensitive phosphorus reagents without the need for anhydrous or inert conditions. Herein, we report the use of ionic liquids as both storage and reaction media which allows difficult and sensitive chemistry to be achieved in a more accessible manner.

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SN - 978-1-60768-176-2

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BT - MOLTEN SALTS AND IONIC LIQUIDS 17

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Amigues EJ, Hardacre C, Keane G, Migaud ME, Norman SE, Pitner WR. Controlled chemistry of Moisture Sensitive Reagents in Ionic Liquids. In Fox DM, Mizuhata M, DeLong HC, Mantz RA, Trulove PC, editors, MOLTEN SALTS AND IONIC LIQUIDS 17. PENNINGTON: ELECTROCHEMICAL SOC INC. 2010. p. 63-72 https://doi.org/10.1149/1.3484762