Abstract
Many reactions involving phosphorus reagents require highly anhydrous and inert conditions for their successful implementation. In particular, the use of PCl3 and its derivatives for synthesis is often hampered by the inherent sensitivity of the materials themselves. Ionic liquids are emerging as green alternative solvents for a range of processes, and in particular have proven to be excellent media for highly sensitive phosphorus reagents without the need for anhydrous or inert conditions. Herein, we report the use of ionic liquids as both storage and reaction media which allows difficult and sensitive chemistry to be achieved in a more accessible manner.
Original language | English |
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Title of host publication | MOLTEN SALTS AND IONIC LIQUIDS 17 |
Editors | DM Fox, M Mizuhata, HC DeLong, RA Mantz, PC Trulove |
Place of Publication | PENNINGTON |
Publisher | ELECTROCHEMICAL SOC INC |
Pages | 63-72 |
Number of pages | 10 |
ISBN (Print) | 978-1-60768-176-2 |
DOIs | |
Publication status | Published - 2010 |
Event | 218th Electrochemical Society Meeting - Las Vegas, United States Duration: 10 Oct 2010 → 15 Oct 2010 https://www.electrochem.org/218 |
Conference
Conference | 218th Electrochemical Society Meeting |
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Abbreviated title | ECS |
Country/Territory | United States |
City | Las Vegas |
Period | 10/10/2010 → 15/10/2010 |
Internet address |