Controlling chlorination versus cyclosulfonation of cis-diols using ionic liquid solvents

Christopher Hardacre; Marie E. Migaud; Kerry Anne Ness

doi:10.1039/c2nj40180k

Controlling chlorination versus cyclosulfonation of cis-diols using ionic liquid solvents

Christopher Hardacre^*, Marie E. Migaud, Kerry Anne Ness

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Diol reactivity can be manipulated in ionic liquids to selectively give chlorinated or cyclic sulfite/sulfate products depending on the ionic liquid used and the presence or absence of base. In comparison with reactions in dichloromethane, the ionic liquid mediated reactions show greatly improved yields and product stability.

Original language	English
Pages (from-to)	2316-2321
Number of pages	6
Journal	New Journal of Chemistry
Volume	36
Issue number	11
DOIs	https://doi.org/10.1039/c2nj40180k
Publication status	Published - Nov 2012

Keywords

NUCLEOPHILIC-SUBSTITUTION REACTIONS
ROOM-TEMPERATURE
ALKYL-HALIDES
ALCOHOLS
CONVERSION
SERIES
MEDIA

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title = "Controlling chlorination versus cyclosulfonation of cis-diols using ionic liquid solvents",

abstract = "Diol reactivity can be manipulated in ionic liquids to selectively give chlorinated or cyclic sulfite/sulfate products depending on the ionic liquid used and the presence or absence of base. In comparison with reactions in dichloromethane, the ionic liquid mediated reactions show greatly improved yields and product stability.",

keywords = "NUCLEOPHILIC-SUBSTITUTION REACTIONS, ROOM-TEMPERATURE, ALKYL-HALIDES, ALCOHOLS, CONVERSION, SERIES, MEDIA",

author = "Christopher Hardacre and Migaud, {Marie E.} and Ness, {Kerry Anne}",

year = "2012",

month = nov,

doi = "10.1039/c2nj40180k",

language = "English",

volume = "36",

pages = "2316--2321",

journal = "New Journal of Chemistry",

issn = "1144-0546",

publisher = "Royal Society of Chemistry",

number = "11",

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TY - JOUR

T1 - Controlling chlorination versus cyclosulfonation of cis-diols using ionic liquid solvents

AU - Hardacre, Christopher

AU - Migaud, Marie E.

AU - Ness, Kerry Anne

PY - 2012/11

Y1 - 2012/11

N2 - Diol reactivity can be manipulated in ionic liquids to selectively give chlorinated or cyclic sulfite/sulfate products depending on the ionic liquid used and the presence or absence of base. In comparison with reactions in dichloromethane, the ionic liquid mediated reactions show greatly improved yields and product stability.

AB - Diol reactivity can be manipulated in ionic liquids to selectively give chlorinated or cyclic sulfite/sulfate products depending on the ionic liquid used and the presence or absence of base. In comparison with reactions in dichloromethane, the ionic liquid mediated reactions show greatly improved yields and product stability.

KW - NUCLEOPHILIC-SUBSTITUTION REACTIONS

KW - ROOM-TEMPERATURE

KW - ALKYL-HALIDES

KW - ALCOHOLS

KW - CONVERSION

KW - SERIES

KW - MEDIA

U2 - 10.1039/c2nj40180k

DO - 10.1039/c2nj40180k

M3 - Article

SN - 1144-0546

VL - 36

SP - 2316

EP - 2321

JO - New Journal of Chemistry

JF - New Journal of Chemistry

IS - 11

ER -

Controlling chlorination versus cyclosulfonation of cis-diols using ionic liquid solvents

Abstract

Keywords

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