Controlling the Sulfur Poisoning of Ag/Al2O3 Catalysts for the Hydrocarbon SCR Reaction by Using a Regenerable SOx Trap

Sarayute Chansai; Robbie Burch; Christopher Hardacre

doi:10.1007/s11244-013-9961-0

Controlling the Sulfur Poisoning of Ag/Al2O3 Catalysts for the Hydrocarbon SCR Reaction by Using a Regenerable SOx Trap

Sarayute Chansai^*, Robbie Burch, Christopher Hardacre

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

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Abstract

The deactivation of a silver-based hydrocarbon selective catalytic reduction catalyst by SOx and the subsequent regeneration under various operating conditions has been investigated. Using a sulfur trap based on a silica-supported catalyst it was found that, for a Ag/SiO2 + Ag/Al2O3 combination, the negative effect of SO2 on the n-octane-SCR reaction can be eliminated under normal operating conditions. The trap can be regenerated by hydrogen at low temperatures or at higher temperatures using a hydrocarbon reductant.

Original language	English
Pages (from-to)	243-248
Number of pages	6
Journal	Topics in Catalysis
Volume	56
Issue number	1-8
Early online date	01 Mar 2013
DOIs	https://doi.org/10.1007/s11244-013-9961-0
Publication status	Published - May 2013
Event	9th International Congress on Catalysis and Automotive Pollution Control (CAPoC) - Brussels, Belgium Duration: 29 Aug 2012 → 31 Aug 2012

Keywords

TOLERANCE
DEACTIVATION
HC-SCR
H-2
PROMOTION
n-octane
SELECTIVE REDUCTION
AG/GAMMA-AL2O3
ALUMINA CATALYSTS
Ag catalysts
SOx trap
Regeneration
SILVER CATALYSTS
HYDROGEN
NOx reduction
NOX REDUCTION

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1007/s11244-013-9961-0

Controlling the Sulfur Poisoning of Ag/Al2O3 Catalysts for the Hydrocarbon SCR Reaction by Using a Regenerable SOx Trap.
Copyright 2013 Springer The final publication is available at Springer via http://dx.doi.org/10.1007/s11244-013-9961-0
Submitted manuscript, 337 KB

Cite this

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title = "Controlling the Sulfur Poisoning of Ag/Al2O3 Catalysts for the Hydrocarbon SCR Reaction by Using a Regenerable SOx Trap",

abstract = "The deactivation of a silver-based hydrocarbon selective catalytic reduction catalyst by SOx and the subsequent regeneration under various operating conditions has been investigated. Using a sulfur trap based on a silica-supported catalyst it was found that, for a Ag/SiO2 + Ag/Al2O3 combination, the negative effect of SO2 on the n-octane-SCR reaction can be eliminated under normal operating conditions. The trap can be regenerated by hydrogen at low temperatures or at higher temperatures using a hydrocarbon reductant.",

keywords = "TOLERANCE, DEACTIVATION, HC-SCR, H-2, PROMOTION, n-octane, SELECTIVE REDUCTION, AG/GAMMA-AL2O3, ALUMINA CATALYSTS, Ag catalysts, SOx trap, Regeneration, SILVER CATALYSTS, HYDROGEN, NOx reduction, NOX REDUCTION",

author = "Sarayute Chansai and Robbie Burch and Christopher Hardacre",

year = "2013",

month = may,

doi = "10.1007/s11244-013-9961-0",

language = "English",

volume = "56",

pages = "243--248",

journal = "Topics in Catalysis",

issn = "1022-5528",

publisher = "Springer",

number = "1-8",

note = "9th International Congress on Catalysis and Automotive Pollution Control (CAPoC) ; Conference date: 29-08-2012 Through 31-08-2012",

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TY - JOUR

T1 - Controlling the Sulfur Poisoning of Ag/Al2O3 Catalysts for the Hydrocarbon SCR Reaction by Using a Regenerable SOx Trap

AU - Chansai, Sarayute

AU - Burch, Robbie

AU - Hardacre, Christopher

PY - 2013/5

Y1 - 2013/5

N2 - The deactivation of a silver-based hydrocarbon selective catalytic reduction catalyst by SOx and the subsequent regeneration under various operating conditions has been investigated. Using a sulfur trap based on a silica-supported catalyst it was found that, for a Ag/SiO2 + Ag/Al2O3 combination, the negative effect of SO2 on the n-octane-SCR reaction can be eliminated under normal operating conditions. The trap can be regenerated by hydrogen at low temperatures or at higher temperatures using a hydrocarbon reductant.

AB - The deactivation of a silver-based hydrocarbon selective catalytic reduction catalyst by SOx and the subsequent regeneration under various operating conditions has been investigated. Using a sulfur trap based on a silica-supported catalyst it was found that, for a Ag/SiO2 + Ag/Al2O3 combination, the negative effect of SO2 on the n-octane-SCR reaction can be eliminated under normal operating conditions. The trap can be regenerated by hydrogen at low temperatures or at higher temperatures using a hydrocarbon reductant.

KW - TOLERANCE

KW - DEACTIVATION

KW - HC-SCR

KW - H-2

KW - PROMOTION

KW - n-octane

KW - SELECTIVE REDUCTION

KW - AG/GAMMA-AL2O3

KW - ALUMINA CATALYSTS

KW - Ag catalysts

KW - SOx trap

KW - Regeneration

KW - SILVER CATALYSTS

KW - HYDROGEN

KW - NOx reduction

KW - NOX REDUCTION

U2 - 10.1007/s11244-013-9961-0

DO - 10.1007/s11244-013-9961-0

M3 - Article

SN - 1022-5528

VL - 56

SP - 243

EP - 248

JO - Topics in Catalysis

JF - Topics in Catalysis

IS - 1-8

T2 - 9th International Congress on Catalysis and Automotive Pollution Control (CAPoC)

Y2 - 29 August 2012 through 31 August 2012

ER -

Controlling the Sulfur Poisoning of Ag/Al2O3 Catalysts for the Hydrocarbon SCR Reaction by Using a Regenerable SOx Trap

Abstract

Keywords

ASJC Scopus subject areas

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