CONVENIENT ONE-POT SYNTHESIS OF HEXA-N-BUTYLDITIN FROM BIS(TRI-N-BUTYLTIN) OXIDE

H MCALONAN, PJ STEVENSON, Paul Stevenson

Research output: Contribution to journalComment/debate

9 Citations (Scopus)

Abstract

Hexa-n-butylditin is prepared in high yield (83%), by reduction of bis(tri-n-butyltin) oxide with sodium borohydride in ethanol. The first stage is reduction. to tri-n-butyltin hydride (not isolated), which rapidly gives hexa-n-butylditin with the Loss of hydrogen under the basic reaction conditions.

Original languageEnglish
Pages (from-to)4021-4022
Number of pages2
JournalOrganometallics
Volume14
Issue number8
Publication statusPublished - Aug 1995

Keywords

  • ORGANOTIN COMPOUNDS
  • PALLADIUM
  • HEXAALKYLDITINS
  • ALKYNES
  • NMR

Cite this

MCALONAN, H ; STEVENSON, PJ ; Stevenson, Paul. / CONVENIENT ONE-POT SYNTHESIS OF HEXA-N-BUTYLDITIN FROM BIS(TRI-N-BUTYLTIN) OXIDE. In: Organometallics. 1995 ; Vol. 14, No. 8. pp. 4021-4022.
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abstract = "Hexa-n-butylditin is prepared in high yield (83{\%}), by reduction of bis(tri-n-butyltin) oxide with sodium borohydride in ethanol. The first stage is reduction. to tri-n-butyltin hydride (not isolated), which rapidly gives hexa-n-butylditin with the Loss of hydrogen under the basic reaction conditions.",
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author = "H MCALONAN and PJ STEVENSON and Paul Stevenson",
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volume = "14",
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journal = "Organometallics",
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CONVENIENT ONE-POT SYNTHESIS OF HEXA-N-BUTYLDITIN FROM BIS(TRI-N-BUTYLTIN) OXIDE. / MCALONAN, H; STEVENSON, PJ; Stevenson, Paul.

In: Organometallics, Vol. 14, No. 8, 08.1995, p. 4021-4022.

Research output: Contribution to journalComment/debate

TY - JOUR

T1 - CONVENIENT ONE-POT SYNTHESIS OF HEXA-N-BUTYLDITIN FROM BIS(TRI-N-BUTYLTIN) OXIDE

AU - MCALONAN, H

AU - STEVENSON, PJ

AU - Stevenson, Paul

PY - 1995/8

Y1 - 1995/8

N2 - Hexa-n-butylditin is prepared in high yield (83%), by reduction of bis(tri-n-butyltin) oxide with sodium borohydride in ethanol. The first stage is reduction. to tri-n-butyltin hydride (not isolated), which rapidly gives hexa-n-butylditin with the Loss of hydrogen under the basic reaction conditions.

AB - Hexa-n-butylditin is prepared in high yield (83%), by reduction of bis(tri-n-butyltin) oxide with sodium borohydride in ethanol. The first stage is reduction. to tri-n-butyltin hydride (not isolated), which rapidly gives hexa-n-butylditin with the Loss of hydrogen under the basic reaction conditions.

KW - ORGANOTIN COMPOUNDS

KW - PALLADIUM

KW - HEXAALKYLDITINS

KW - ALKYNES

KW - NMR

M3 - Comment/debate

VL - 14

SP - 4021

EP - 4022

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 8

ER -