Conventional free radical polymerization in room temperature ionic liquids: a green approach to commodity polymers with practical advantages

H.L. Hong; H.W. Zhang; J.W. Mays; A.E. Visser; C.S. Brazel; John Holbrey; W.M. Reichert; Robin Rogers

doi:10.1039/b204319j

Conventional free radical polymerization in room temperature ionic liquids: a green approach to commodity polymers with practical advantages

H.L. Hong, H.W. Zhang, J.W. Mays, A.E. Visser, C.S. Brazel, John Holbrey, W.M. Reichert, Robin Rogers

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

195 Citations (Scopus)

Abstract

Free-radical polymerization of methyl methacrylate and styrene using conventional organic initiators in the room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ([ C(4)mim][PF6]) is rapid and produces polymers with molecular weights up to 10x higher than from benzene; both polymerization and isolation of products were achieved without using VOCs, offering economic as well as environmental advantages.

Original language	English
Pages (from-to)	1368-1369
Number of pages	2
Journal	Chemical Communications
Volume	2002
DOIs	https://doi.org/10.1039/b204319j
Publication status	Published - 2002

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title = "Conventional free radical polymerization in room temperature ionic liquids: a green approach to commodity polymers with practical advantages",

abstract = "Free-radical polymerization of methyl methacrylate and styrene using conventional organic initiators in the room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ([ C(4)mim][PF6]) is rapid and produces polymers with molecular weights up to 10x higher than from benzene; both polymerization and isolation of products were achieved without using VOCs, offering economic as well as environmental advantages.",

author = "H.L. Hong and H.W. Zhang and J.W. Mays and A.E. Visser and C.S. Brazel and John Holbrey and W.M. Reichert and Robin Rogers",

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AU - Hong, H.L.

AU - Zhang, H.W.

AU - Mays, J.W.

AU - Visser, A.E.

AU - Brazel, C.S.

AU - Holbrey, John

AU - Reichert, W.M.

AU - Rogers, Robin

PY - 2002

Y1 - 2002

N2 - Free-radical polymerization of methyl methacrylate and styrene using conventional organic initiators in the room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ([ C(4)mim][PF6]) is rapid and produces polymers with molecular weights up to 10x higher than from benzene; both polymerization and isolation of products were achieved without using VOCs, offering economic as well as environmental advantages.

AB - Free-radical polymerization of methyl methacrylate and styrene using conventional organic initiators in the room temperature ionic liquid, 1-butyl-3-methylimidazolium hexafluorophosphate ([ C(4)mim][PF6]) is rapid and produces polymers with molecular weights up to 10x higher than from benzene; both polymerization and isolation of products were achieved without using VOCs, offering economic as well as environmental advantages.

U2 - 10.1039/b204319j

DO - 10.1039/b204319j

M3 - Article

SN - 1359-7345

VL - 2002

SP - 1368

EP - 1369

JO - Chemical Communications

JF - Chemical Communications

ER -

Conventional free radical polymerization in room temperature ionic liquids: a green approach to commodity polymers with practical advantages

Abstract

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