Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(I) oxide

Andrew C. Marr, Patrick J. Morgan, Graham C. Saunders, Hayden P. Thomas

Research output: Contribution to journalArticle

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Abstract

The reaction between haloform, the complexes [Cp*IrCl2(κC-MeNC3H2NCH2Ar)] (Ar = C6H3F2-2,6, C6H3F-2-Cl-6, C6H3Me2-2,6) and silver(I) oxide proceeded by carbon─halogen bond fission to yield the carbonate complexes [Cp*Ir(κ2O-CO3)(κC-MeNC3H2NCH2Ar)].
Original languageEnglish
JournalDalton Transactions
Early online date08 Jan 2019
DOIs
Publication statusEarly online date - 08 Jan 2019

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