Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(I) oxide

Andrew C. Marr, Patrick J. Morgan, Graham C. Saunders, Hayden P. Thomas

Research output: Contribution to journalArticle

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Abstract

The reaction between haloform, the complexes [Cp*IrCl2(κC-MeNC3H2NCH2Ar)] (Ar = C6H3F2-2,6, C6H3F-2-Cl-6, C6H3Me2-2,6) and silver(I) oxide proceeded by carbon─halogen bond fission to yield the carbonate complexes [Cp*Ir(κ2O-CO3)(κC-MeNC3H2NCH2Ar)].
Original languageEnglish
JournalDalton Transactions
Early online date08 Jan 2019
DOIs
Publication statusEarly online date - 08 Jan 2019

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Iridium
Carbonates
Silver
Oxides
carbene

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title = "Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(I) oxide",
abstract = "The reaction between haloform, the complexes [Cp*IrCl2(κC-MeNC3H2NCH2Ar)] (Ar = C6H3F2-2,6, C6H3F-2-Cl-6, C6H3Me2-2,6) and silver(I) oxide proceeded by carbon─halogen bond fission to yield the carbonate complexes [Cp*Ir(κ2O-CO3)(κC-MeNC3H2NCH2Ar)].",
author = "Marr, {Andrew C.} and Morgan, {Patrick J.} and Saunders, {Graham C.} and Thomas, {Hayden P.}",
year = "2019",
month = "1",
day = "8",
doi = "10.1039/C8DT04456B",
language = "English",
journal = "Dalton transactions (Cambridge, England : 2003)",
issn = "1477-9226",
publisher = "The Royal Society of Chemistry",

}

Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(I) oxide. / Marr, Andrew C.; Morgan, Patrick J.; Saunders, Graham C.; Thomas, Hayden P.

In: Dalton Transactions, 08.01.2019.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Conversion of haloform to carbonate by iridium N-heterocyclic carbene complexes and silver(I) oxide

AU - Marr, Andrew C.

AU - Morgan, Patrick J.

AU - Saunders, Graham C.

AU - Thomas, Hayden P.

PY - 2019/1/8

Y1 - 2019/1/8

N2 - The reaction between haloform, the complexes [Cp*IrCl2(κC-MeNC3H2NCH2Ar)] (Ar = C6H3F2-2,6, C6H3F-2-Cl-6, C6H3Me2-2,6) and silver(I) oxide proceeded by carbon─halogen bond fission to yield the carbonate complexes [Cp*Ir(κ2O-CO3)(κC-MeNC3H2NCH2Ar)].

AB - The reaction between haloform, the complexes [Cp*IrCl2(κC-MeNC3H2NCH2Ar)] (Ar = C6H3F2-2,6, C6H3F-2-Cl-6, C6H3Me2-2,6) and silver(I) oxide proceeded by carbon─halogen bond fission to yield the carbonate complexes [Cp*Ir(κ2O-CO3)(κC-MeNC3H2NCH2Ar)].

U2 - 10.1039/C8DT04456B

DO - 10.1039/C8DT04456B

M3 - Article

JO - Dalton transactions (Cambridge, England : 2003)

JF - Dalton transactions (Cambridge, England : 2003)

SN - 1477-9226

ER -