Copper complexes with new pyridylpyrazole based ligands

José A. Campo; Mercedes Cano; José V. Heras; M. Cristina Lagunas; Josefina Perles; Elena Pinilla; M. Rosario Torres

doi:10.1002/1522-2675(200204)85:4<1079::AID-HLCA1079>3.0.CO;2-G

Copper complexes with new pyridylpyrazole based ligands

José A. Campo, Mercedes Cano^*, José V. Heras, M. Cristina Lagunas, Josefina Perles, Elena Pinilla, M. Rosario Torres

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

23 Citations (Scopus)

Abstract

We report the synthesis, characterization, and crystal structures of new ligands of the pyridinylpyrazole type, i.e., 3,5-bis(4-butoxyphenyl)-1-(pyridin-2-y1)-1H-pyrazole (L¹) and 3,5-bis(4-phenoxyphenyl)-1-(pyridin-2-y1)-1H-pyrazole (L²) (Scheme 1), and the study of their coordination behavior towards Cu¹ and Cu¹¹. The versatility of this type of ligand, which can give access to different coordination spheres about the metal center, depending on the nature of the copper starting material used in the preparation of the complexes (Scheme 2), is illustrated. Thus, pseudo-tetrahedral Cu¹ as well as six-coordinated tetragonal and distorted tetragonal pyramidal Cu¹¹ derivatives were obtained for [Cu(L)₂]PF₆, [Cu(Cl)₂(L)₂] (L = L¹, L²), and [Cu(Cl)(L¹)₂]PF₆, respectively. We also present a crystallographic support of a distorted octahedral cis-bis(tetrafluoroborato-κF)copper(II) compound found for [Cu(BF₄)₂(L¹)₂] (3).

Original language	English
Pages (from-to)	1079-1095
Number of pages	17
Journal	Helvetica Chimica Acta
Volume	85
Issue number	4
DOIs	https://doi.org/10.1002/1522-2675(200204)85:4<1079::AID-HLCA1079>3.0.CO;2-G
Publication status	Published - 13 May 2002
Externally published	Yes

ASJC Scopus subject areas

Catalysis
Biochemistry
Drug Discovery
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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10.1002/1522-2675(200204)85:4<1079::AID-HLCA1079>3.0.CO;2-G

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@article{99862fa6fcaa42348817f6ee280294a7,

title = "Copper complexes with new pyridylpyrazole based ligands",

abstract = "We report the synthesis, characterization, and crystal structures of new ligands of the pyridinylpyrazole type, i.e., 3,5-bis(4-butoxyphenyl)-1-(pyridin-2-y1)-1H-pyrazole (L1) and 3,5-bis(4-phenoxyphenyl)-1-(pyridin-2-y1)-1H-pyrazole (L2) (Scheme 1), and the study of their coordination behavior towards Cu1 and Cu11. The versatility of this type of ligand, which can give access to different coordination spheres about the metal center, depending on the nature of the copper starting material used in the preparation of the complexes (Scheme 2), is illustrated. Thus, pseudo-tetrahedral Cu1 as well as six-coordinated tetragonal and distorted tetragonal pyramidal Cu11 derivatives were obtained for [Cu(L)2]PF6, [Cu(Cl)2(L)2] (L = L1, L2), and [Cu(Cl)(L1)2]PF6, respectively. We also present a crystallographic support of a distorted octahedral cis-bis(tetrafluoroborato-κF)copper(II) compound found for [Cu(BF4)2(L1)2] (3).",

author = "Campo, {Jos{\'e} A.} and Mercedes Cano and Heras, {Jos{\'e} V.} and Lagunas, {M. Cristina} and Josefina Perles and Elena Pinilla and Torres, {M. Rosario}",

year = "2002",

month = may,

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doi = "10.1002/1522-2675(200204)85:4<1079::AID-HLCA1079>3.0.CO;2-G",

language = "English",

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pages = "1079--1095",

journal = "Helvetica Chimica Acta",

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TY - JOUR

T1 - Copper complexes with new pyridylpyrazole based ligands

AU - Campo, José A.

AU - Cano, Mercedes

AU - Heras, José V.

AU - Lagunas, M. Cristina

AU - Perles, Josefina

AU - Pinilla, Elena

AU - Torres, M. Rosario

PY - 2002/5/13

Y1 - 2002/5/13

N2 - We report the synthesis, characterization, and crystal structures of new ligands of the pyridinylpyrazole type, i.e., 3,5-bis(4-butoxyphenyl)-1-(pyridin-2-y1)-1H-pyrazole (L1) and 3,5-bis(4-phenoxyphenyl)-1-(pyridin-2-y1)-1H-pyrazole (L2) (Scheme 1), and the study of their coordination behavior towards Cu1 and Cu11. The versatility of this type of ligand, which can give access to different coordination spheres about the metal center, depending on the nature of the copper starting material used in the preparation of the complexes (Scheme 2), is illustrated. Thus, pseudo-tetrahedral Cu1 as well as six-coordinated tetragonal and distorted tetragonal pyramidal Cu11 derivatives were obtained for [Cu(L)2]PF6, [Cu(Cl)2(L)2] (L = L1, L2), and [Cu(Cl)(L1)2]PF6, respectively. We also present a crystallographic support of a distorted octahedral cis-bis(tetrafluoroborato-κF)copper(II) compound found for [Cu(BF4)2(L1)2] (3).

AB - We report the synthesis, characterization, and crystal structures of new ligands of the pyridinylpyrazole type, i.e., 3,5-bis(4-butoxyphenyl)-1-(pyridin-2-y1)-1H-pyrazole (L1) and 3,5-bis(4-phenoxyphenyl)-1-(pyridin-2-y1)-1H-pyrazole (L2) (Scheme 1), and the study of their coordination behavior towards Cu1 and Cu11. The versatility of this type of ligand, which can give access to different coordination spheres about the metal center, depending on the nature of the copper starting material used in the preparation of the complexes (Scheme 2), is illustrated. Thus, pseudo-tetrahedral Cu1 as well as six-coordinated tetragonal and distorted tetragonal pyramidal Cu11 derivatives were obtained for [Cu(L)2]PF6, [Cu(Cl)2(L)2] (L = L1, L2), and [Cu(Cl)(L1)2]PF6, respectively. We also present a crystallographic support of a distorted octahedral cis-bis(tetrafluoroborato-κF)copper(II) compound found for [Cu(BF4)2(L1)2] (3).

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U2 - 10.1002/1522-2675(200204)85:4<1079::AID-HLCA1079>3.0.CO;2-G

DO - 10.1002/1522-2675(200204)85:4<1079::AID-HLCA1079>3.0.CO;2-G

M3 - Article

AN - SCOPUS:0036237819

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VL - 85

SP - 1079

EP - 1095

JO - Helvetica Chimica Acta

JF - Helvetica Chimica Acta

IS - 4

ER -

Copper complexes with new pyridylpyrazole based ligands

Abstract

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