Copper(I)/ketoABNO Catalysed Aerobic Alcohol Oxidation

Luke Rogan, Nicola Hughes, Qun Cao, Laura Dornan, Mark Muldoon

Research output: Contribution to journalArticle

28 Citations (Scopus)

Abstract

A Cu(I)/9-azabicyclo[3.3.1]nonan-3-one N-oxyl (ketoABNO) aerobic catalyst system is highly effective for the oxidation of secondary alcohols, including unactivated aliphatic substrates. The effects of pressure and gas composition on catalyst performance are examined. The radical can be employed at low loadings and is also amenable to immobilisation on to solid supports.
Original languageEnglish
Pages (from-to)1720-1725
JournalCatalysis, Science & technology
Volume4
DOIs
Publication statusPublished - 17 Mar 2014

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