The initial rate of the photocatalysed oxidation of methylene blue, MB, by dissolved oxygen in solution, ri(MB), is measured for a series of titania on glass samples exhibiting a wide range of activities. The samples used include two different types of commercial self-cleaning glass and a lab-made sol-geltitania film. The activities of these samples are also assessed using a resazurin-based photocatalyst activity indicator ink, i.e. Rz paii, for which the initial rates of the photocatalysed reduction of Rz were measured, ri(Rz). A plot of ri(MB)vs. ri(Rz) reveals a goodstraight line, thereby demonstrating a linear correlation (for TiO2films on glass at least) between the slow (usually hours) photocatalysed oxidation of organic materials, such as MB, and the fast (typically minutes) photocatalysed irreversible reduction of a dye, like Rz, in a paii. The possible use of paii technology for assessing, in a simple, quick and inexpensive manner, photocatalytic films both in the laboratory and in situ is discussed briefly.
|Number of pages||4|
|Journal||Journal of Photochemistry and Photobiology A: Chemistry|
|Early online date||25 Jul 2016|
|Publication status||Published - 01 Nov 2016|
Correlation between the photocatalysed oxidation of methylene blue in solution and the reduction of resazurin in a photocatalyst activity indicator ink (Rz Paii)
Mills, A. (Creator), Queen's University Belfast, 22 Jul 2016