Crystal polymorphism in 1-butyl-3-methylimidazolium halides: supporting ionic liquid formation by inhibition of crystallization

John Holbrey; W.M. Reichert; Mark Nieuwenhuyzen; S. Johnston; Kenneth Seddon; R.D. Rogers

doi:10.1039/b304543a

Crystal polymorphism in 1-butyl-3-methylimidazolium halides: supporting ionic liquid formation by inhibition of crystallization

John Holbrey, W.M. Reichert, Mark Nieuwenhuyzen, S. Johnston, Kenneth Seddon, R.D. Rogers

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

350 Citations (Scopus)

Abstract

Crystallization of 1-butyl-3-methylimidazolium chloride from mixed ionic liquid or ionic liquid-aromatic solution, and from the melt yields different crystalline polymorphs, the first direct evidence for inhibition of crystallization in ionic liquids by polymorphism.

Original language	English
Pages (from-to)	1636-1637
Number of pages	2
Journal	Chemical Communications
Volume	9
Issue number	14
DOIs	https://doi.org/10.1039/b304543a
Publication status	Published - 21 Jul 2003

ASJC Scopus subject areas

Chemistry(all)

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10.1039/b304543a

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title = "Crystal polymorphism in 1-butyl-3-methylimidazolium halides: supporting ionic liquid formation by inhibition of crystallization",

abstract = "Crystallization of 1-butyl-3-methylimidazolium chloride from mixed ionic liquid or ionic liquid-aromatic solution, and from the melt yields different crystalline polymorphs, the first direct evidence for inhibition of crystallization in ionic liquids by polymorphism.",

author = "John Holbrey and W.M. Reichert and Mark Nieuwenhuyzen and S. Johnston and Kenneth Seddon and R.D. Rogers",

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AU - Seddon, Kenneth

AU - Rogers, R.D.

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AB - Crystallization of 1-butyl-3-methylimidazolium chloride from mixed ionic liquid or ionic liquid-aromatic solution, and from the melt yields different crystalline polymorphs, the first direct evidence for inhibition of crystallization in ionic liquids by polymorphism.

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