Cyclometalation via Carbon–Fluorine Bond Activation Induced by Silver Particles

Hayden Thomas, Yue-ming Wang, Fabio Lorenzini, Simon J. Coles, Peter N. Horton, Andrew C. Marr, Graham C. Saunders

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)
149 Downloads (Pure)

Abstract

On treatment with either freshly prepared silver nanoparticles or silver particles mechanochemically generated by stirring silver(I) oxide in dichloromethane, the complex [Cp*IrCl2(κC-MeNC3H2NCH2C6F5)] underwent a rapid and clean cyclometalation involving carbon—fluorine bond fission to afford the product [Cp*IrCl(κC2-MeNC3H2NCH2C6F4)].
Original languageEnglish
Pages (from-to)960-963
Number of pages4
JournalOrganometallics
Volume36
Issue number5
Early online date27 Feb 2017
DOIs
Publication statusPublished - 13 Mar 2017

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