Cyclometalation via Carbon–Fluorine Bond Activation Induced by Silver Particles

Hayden Thomas; Yue-ming Wang; Fabio Lorenzini; Simon J. Coles; Peter N. Horton; Andrew C.  Marr; Graham C. Saunders

doi:10.1021/acs.organomet.6b00872

Cyclometalation via Carbon–Fluorine Bond Activation Induced by Silver Particles

Hayden Thomas
, Yue-ming Wang
, Fabio Lorenzini
, Simon J. Coles
, Peter N. Horton
, Andrew C. Marr
, Graham C. Saunders

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

459 Downloads (Pure)

Abstract

On treatment with either freshly prepared silver nanoparticles or silver particles mechanochemically generated by stirring silver(I) oxide in dichloromethane, the complex [Cp*IrCl2(κC-MeNC3H2NCH2C6F5)] underwent a rapid and clean cyclometalation involving carbon—fluorine bond fission to afford the product [Cp*IrCl(κC2-MeNC3H2NCH2C6F4)].

Original language	English
Pages (from-to)	960-963
Number of pages	4
Journal	Organometallics
Volume	36
Issue number	5
Early online date	27 Feb 2017
DOIs	https://doi.org/10.1021/acs.organomet.6b00872
Publication status	Published - 13 Mar 2017

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Cyclometallation via Carbon–Fluorine Bond Activation Induced by Silver Particles
Copyright 2017 American Chemical Society. This work is made available online in accordance with the publisher’s policies. Please refer to any applicable terms of use of the publisher.
Accepted author manuscript, 552 KBLicence: Unspecified

Cite this

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title = "Cyclometalation via Carbon{\textendash}Fluorine Bond Activation Induced by Silver Particles",

abstract = "On treatment with either freshly prepared silver nanoparticles or silver particles mechanochemically generated by stirring silver(I) oxide in dichloromethane, the complex [Cp*IrCl2(κC-MeNC3H2NCH2C6F5)] underwent a rapid and clean cyclometalation involving carbon{\textemdash}fluorine bond fission to afford the product [Cp*IrCl(κC2-MeNC3H2NCH2C6F4)].",

author = "Hayden Thomas and Yue-ming Wang and Fabio Lorenzini and Coles, \{Simon J.\} and Horton, \{Peter N.\} and Marr, \{Andrew C.\} and Saunders, \{Graham C.\}",

year = "2017",

month = mar,

day = "13",

doi = "10.1021/acs.organomet.6b00872",

language = "English",

volume = "36",

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journal = "Organometallics",

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T1 - Cyclometalation via Carbon–Fluorine Bond Activation Induced by Silver Particles

AU - Thomas, Hayden

AU - Wang, Yue-ming

AU - Lorenzini, Fabio

AU - Coles, Simon J.

AU - Horton, Peter N.

AU - Marr, Andrew C.

AU - Saunders, Graham C.

PY - 2017/3/13

Y1 - 2017/3/13

N2 - On treatment with either freshly prepared silver nanoparticles or silver particles mechanochemically generated by stirring silver(I) oxide in dichloromethane, the complex [Cp*IrCl2(κC-MeNC3H2NCH2C6F5)] underwent a rapid and clean cyclometalation involving carbon—fluorine bond fission to afford the product [Cp*IrCl(κC2-MeNC3H2NCH2C6F4)].

AB - On treatment with either freshly prepared silver nanoparticles or silver particles mechanochemically generated by stirring silver(I) oxide in dichloromethane, the complex [Cp*IrCl2(κC-MeNC3H2NCH2C6F5)] underwent a rapid and clean cyclometalation involving carbon—fluorine bond fission to afford the product [Cp*IrCl(κC2-MeNC3H2NCH2C6F4)].

UR - http://pubs.acs.org/doi/suppl/10.1021/acs.organomet.6b00872

U2 - 10.1021/acs.organomet.6b00872

DO - 10.1021/acs.organomet.6b00872

M3 - Article

SN - 0276-7333

VL - 36

SP - 960

EP - 963

JO - Organometallics

JF - Organometallics

IS - 5

ER -

Cyclometalation via Carbon–Fluorine Bond Activation Induced by Silver Particles

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Andrew C. Marr

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Cyclometalation via Carbon–Fluorine Bond Activation Induced by Silver Particles

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