Determination of hydrogen sulfide in wines based on chemical-derivatization-triggered aggregation-induced emission by high-performance liquid chromatography with fluorescence detection

Yanxin Yu; Guoliang Li; Di Wu; Fuping Zheng; Xianlong Zhang; Jianghua Liu; Na Hu; Honglun Wang; Yongning Wu

doi:10.1021/acs.jafc.9b04454

Determination of hydrogen sulfide in wines based on chemical-derivatization-triggered aggregation-induced emission by high-performance liquid chromatography with fluorescence detection

Yanxin Yu, Guoliang Li^*, Di Wu, Fuping Zheng, Xianlong Zhang, Jianghua Liu, Na Hu, Honglun Wang, Yongning Wu

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

A chemical-derivatization-triggered aggregation-induced emission (AIE) method for the highly selective determination of hydrogen sulfide (H₂S) in wine matrices by high-performance liquid chromatography with fluorescence detection (HPLC-FLD) was developed. The detection strategy was developed based on the chemical derivatization of H₂S using a low-cost AIE-active fluorescence derivatization reagent, N-(3-iodine-2-oxopropyl)pyrene methamine (NIPM), to trigger specific AIE at 475 nm, which was red-shifted sharply to the maximum emission wavelength as compared with NIPM monomers of 375 nm, effectively quenching the interference from other thiol-containing compounds. With the aid of specific AIE and the effective separation of HPLC, the proposed method showed high selectivity and sensitivity toward H₂S. The limits of detection (LODs) at the sub-nM level of 0.25 nmol/L in the wine-beer sample and 0.30 nmol/L in red wine sample were obtained. To certify its applicability, this proposed strategy was successfully applied for the determination of H₂S in wine matrices.

Original language	English
Pages (from-to)	876-883
Number of pages	8
Journal	Journal of agricultural and food chemistry
Volume	68
Issue number	3
Early online date	31 Oct 2019
DOIs	https://doi.org/10.1021/acs.jafc.9b04454
Publication status	Published - 22 Jan 2020
Externally published	Yes

Bibliographical note

Funding Information:
This research was funded by the National Natural Science Foundation of China (21677085 and 31801454), the Natural Science Foundation of Shandong Province (ZR2017JL012), the Science and Technology Nova Plan of Shaanxi Province (2019KJXX-010), and the Youth Innovation Team of Shaanxi Universities (Food Quality and Safety Innovation Team).

Publisher Copyright:
Copyright © 2019 American Chemical Society.

Keywords

aggregation-induced emission
fluorescence detection
high-performance liquid chromatography
Hydrogen sulfide

ASJC Scopus subject areas

Chemistry(all)
Agricultural and Biological Sciences(all)

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Cite this

Yu, Y., Li, G., Wu, D., Zheng, F., Zhang, X., Liu, J., Hu, N., Wang, H., & Wu, Y. (2020). Determination of hydrogen sulfide in wines based on chemical-derivatization-triggered aggregation-induced emission by high-performance liquid chromatography with fluorescence detection. Journal of agricultural and food chemistry, 68(3), 876-883. https://doi.org/10.1021/acs.jafc.9b04454

@article{8fed73fa69e6435fa709bd90643eb970,

title = "Determination of hydrogen sulfide in wines based on chemical-derivatization-triggered aggregation-induced emission by high-performance liquid chromatography with fluorescence detection",

abstract = "A chemical-derivatization-triggered aggregation-induced emission (AIE) method for the highly selective determination of hydrogen sulfide (H2S) in wine matrices by high-performance liquid chromatography with fluorescence detection (HPLC-FLD) was developed. The detection strategy was developed based on the chemical derivatization of H2S using a low-cost AIE-active fluorescence derivatization reagent, N-(3-iodine-2-oxopropyl)pyrene methamine (NIPM), to trigger specific AIE at 475 nm, which was red-shifted sharply to the maximum emission wavelength as compared with NIPM monomers of 375 nm, effectively quenching the interference from other thiol-containing compounds. With the aid of specific AIE and the effective separation of HPLC, the proposed method showed high selectivity and sensitivity toward H2S. The limits of detection (LODs) at the sub-nM level of 0.25 nmol/L in the wine-beer sample and 0.30 nmol/L in red wine sample were obtained. To certify its applicability, this proposed strategy was successfully applied for the determination of H2S in wine matrices.",

keywords = "aggregation-induced emission, fluorescence detection, high-performance liquid chromatography, Hydrogen sulfide",

author = "Yanxin Yu and Guoliang Li and Di Wu and Fuping Zheng and Xianlong Zhang and Jianghua Liu and Na Hu and Honglun Wang and Yongning Wu",

note = "Funding Information: This research was funded by the National Natural Science Foundation of China (21677085 and 31801454), the Natural Science Foundation of Shandong Province (ZR2017JL012), the Science and Technology Nova Plan of Shaanxi Province (2019KJXX-010), and the Youth Innovation Team of Shaanxi Universities (Food Quality and Safety Innovation Team). Publisher Copyright: Copyright {\textcopyright} 2019 American Chemical Society.",

year = "2020",

month = jan,

day = "22",

doi = "10.1021/acs.jafc.9b04454",

language = "English",

volume = "68",

pages = "876--883",

journal = "Journal of Agricultural and Food Chemistry",

issn = "0021-8561",

publisher = "American Chemical Society",

number = "3",

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Yu, Y, Li, G, Wu, D, Zheng, F, Zhang, X, Liu, J, Hu, N, Wang, H & Wu, Y 2020, 'Determination of hydrogen sulfide in wines based on chemical-derivatization-triggered aggregation-induced emission by high-performance liquid chromatography with fluorescence detection', Journal of agricultural and food chemistry, vol. 68, no. 3, pp. 876-883. https://doi.org/10.1021/acs.jafc.9b04454

Determination of hydrogen sulfide in wines based on chemical-derivatization-triggered aggregation-induced emission by high-performance liquid chromatography with fluorescence detection. / Yu, Yanxin; Li, Guoliang; Wu, Di et al.

In: Journal of agricultural and food chemistry, Vol. 68, No. 3, 22.01.2020, p. 876-883.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Determination of hydrogen sulfide in wines based on chemical-derivatization-triggered aggregation-induced emission by high-performance liquid chromatography with fluorescence detection

AU - Yu, Yanxin

AU - Li, Guoliang

AU - Wu, Di

AU - Zheng, Fuping

AU - Zhang, Xianlong

AU - Liu, Jianghua

AU - Hu, Na

AU - Wang, Honglun

AU - Wu, Yongning

N1 - Funding Information: This research was funded by the National Natural Science Foundation of China (21677085 and 31801454), the Natural Science Foundation of Shandong Province (ZR2017JL012), the Science and Technology Nova Plan of Shaanxi Province (2019KJXX-010), and the Youth Innovation Team of Shaanxi Universities (Food Quality and Safety Innovation Team). Publisher Copyright: Copyright © 2019 American Chemical Society.

PY - 2020/1/22

Y1 - 2020/1/22

N2 - A chemical-derivatization-triggered aggregation-induced emission (AIE) method for the highly selective determination of hydrogen sulfide (H2S) in wine matrices by high-performance liquid chromatography with fluorescence detection (HPLC-FLD) was developed. The detection strategy was developed based on the chemical derivatization of H2S using a low-cost AIE-active fluorescence derivatization reagent, N-(3-iodine-2-oxopropyl)pyrene methamine (NIPM), to trigger specific AIE at 475 nm, which was red-shifted sharply to the maximum emission wavelength as compared with NIPM monomers of 375 nm, effectively quenching the interference from other thiol-containing compounds. With the aid of specific AIE and the effective separation of HPLC, the proposed method showed high selectivity and sensitivity toward H2S. The limits of detection (LODs) at the sub-nM level of 0.25 nmol/L in the wine-beer sample and 0.30 nmol/L in red wine sample were obtained. To certify its applicability, this proposed strategy was successfully applied for the determination of H2S in wine matrices.

AB - A chemical-derivatization-triggered aggregation-induced emission (AIE) method for the highly selective determination of hydrogen sulfide (H2S) in wine matrices by high-performance liquid chromatography with fluorescence detection (HPLC-FLD) was developed. The detection strategy was developed based on the chemical derivatization of H2S using a low-cost AIE-active fluorescence derivatization reagent, N-(3-iodine-2-oxopropyl)pyrene methamine (NIPM), to trigger specific AIE at 475 nm, which was red-shifted sharply to the maximum emission wavelength as compared with NIPM monomers of 375 nm, effectively quenching the interference from other thiol-containing compounds. With the aid of specific AIE and the effective separation of HPLC, the proposed method showed high selectivity and sensitivity toward H2S. The limits of detection (LODs) at the sub-nM level of 0.25 nmol/L in the wine-beer sample and 0.30 nmol/L in red wine sample were obtained. To certify its applicability, this proposed strategy was successfully applied for the determination of H2S in wine matrices.

KW - aggregation-induced emission

KW - fluorescence detection

KW - high-performance liquid chromatography

KW - Hydrogen sulfide

U2 - 10.1021/acs.jafc.9b04454

DO - 10.1021/acs.jafc.9b04454

M3 - Article

C2 - 31670510

AN - SCOPUS:85078450167

VL - 68

SP - 876

EP - 883

JO - Journal of Agricultural and Food Chemistry

JF - Journal of Agricultural and Food Chemistry

SN - 0021-8561

IS - 3

ER -

Determination of hydrogen sulfide in wines based on chemical-derivatization-triggered aggregation-induced emission by high-performance liquid chromatography with fluorescence detection

Abstract

Bibliographical note

Keywords

ASJC Scopus subject areas

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