Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate

Kristof Van Hecke; Peter Nockemann; Koen Binnemans; Luc Van Meervelt

doi:10.1107/S1600536807002292

Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate

Kristof Van Hecke, Peter Nockemann, Koen Binnemans, Luc Van Meervelt^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

The title compound, [Ni2Cl2(C9H10NO2)(2)]center dot CH3OH, is a dinuclear unit built up by two nickel(II) complexes, bridged by two Cl atoms. The coordination geometry around each Ni-II atom can be considered as distorted square-pyramidal, with the tridendate chelate Schiff base ligands coordinating in a trans conformation through their imine N atom and phenoxy and alkoxy O atoms.

Original language	English
Pages (from-to)	M569-M571
Number of pages	3
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	63
DOIs	https://doi.org/10.1107/S1600536807002292
Publication status	Published - Feb 2007

Keywords

SCHIFF-BASE LIGANDS
CRYSTALLINE-STRUCTURE
STRUCTURAL DIVERSITY
MOLECULAR-STRUCTURE
MAGNETIC-PROPERTIES
SPIN CLUSTERS
COMPLEXES
TETRANUCLEAR
TRINUCLEAR
REACTIVITY

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@article{0a9da68b2eb6491993be2712a21284a2,

title = "Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate",

abstract = "The title compound, [Ni2Cl2(C9H10NO2)(2)]center dot CH3OH, is a dinuclear unit built up by two nickel(II) complexes, bridged by two Cl atoms. The coordination geometry around each Ni-II atom can be considered as distorted square-pyramidal, with the tridendate chelate Schiff base ligands coordinating in a trans conformation through their imine N atom and phenoxy and alkoxy O atoms.",

keywords = "SCHIFF-BASE LIGANDS, CRYSTALLINE-STRUCTURE, STRUCTURAL DIVERSITY, MOLECULAR-STRUCTURE, MAGNETIC-PROPERTIES, SPIN CLUSTERS, COMPLEXES, TETRANUCLEAR, TRINUCLEAR, REACTIVITY",

author = "{Van Hecke}, Kristof and Peter Nockemann and Koen Binnemans and {Van Meervelt}, Luc",

year = "2007",

month = feb,

doi = "10.1107/S1600536807002292",

language = "English",

volume = "63",

pages = "M569--M571",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

}

TY - JOUR

T1 - Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate

AU - Van Hecke, Kristof

AU - Nockemann, Peter

AU - Binnemans, Koen

AU - Van Meervelt, Luc

PY - 2007/2

Y1 - 2007/2

N2 - The title compound, [Ni2Cl2(C9H10NO2)(2)]center dot CH3OH, is a dinuclear unit built up by two nickel(II) complexes, bridged by two Cl atoms. The coordination geometry around each Ni-II atom can be considered as distorted square-pyramidal, with the tridendate chelate Schiff base ligands coordinating in a trans conformation through their imine N atom and phenoxy and alkoxy O atoms.

AB - The title compound, [Ni2Cl2(C9H10NO2)(2)]center dot CH3OH, is a dinuclear unit built up by two nickel(II) complexes, bridged by two Cl atoms. The coordination geometry around each Ni-II atom can be considered as distorted square-pyramidal, with the tridendate chelate Schiff base ligands coordinating in a trans conformation through their imine N atom and phenoxy and alkoxy O atoms.

KW - SCHIFF-BASE LIGANDS

KW - CRYSTALLINE-STRUCTURE

KW - STRUCTURAL DIVERSITY

KW - MOLECULAR-STRUCTURE

KW - MAGNETIC-PROPERTIES

KW - SPIN CLUSTERS

KW - COMPLEXES

KW - TETRANUCLEAR

KW - TRINUCLEAR

KW - REACTIVITY

U2 - 10.1107/S1600536807002292

DO - 10.1107/S1600536807002292

M3 - Article

SN - 1600-5368

VL - 63

SP - M569-M571

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

ER -

Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate

Abstract

Keywords

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