Di-mu-chloro-bis({2-[(2-hydroxyethyl)iminomethyl]phenolato-kappa N-3,O,O '} nickel(II)) methanol solvate

Kristof Van Hecke, Peter Nockemann, Koen Binnemans, Luc Van Meervelt*

*Corresponding author for this work

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

The title compound, [Ni2Cl2(C9H10NO2)(2)]center dot CH3OH, is a dinuclear unit built up by two nickel(II) complexes, bridged by two Cl atoms. The coordination geometry around each Ni-II atom can be considered as distorted square-pyramidal, with the tridendate chelate Schiff base ligands coordinating in a trans conformation through their imine N atom and phenoxy and alkoxy O atoms.

Original languageEnglish
Pages (from-to)M569-M571
Number of pages3
JournalActa Crystallographica Section E: Structure Reports Online
Volume63
DOIs
Publication statusPublished - Feb 2007

Keywords

  • SCHIFF-BASE LIGANDS
  • CRYSTALLINE-STRUCTURE
  • STRUCTURAL DIVERSITY
  • MOLECULAR-STRUCTURE
  • MAGNETIC-PROPERTIES
  • SPIN CLUSTERS
  • COMPLEXES
  • TETRANUCLEAR
  • TRINUCLEAR
  • REACTIVITY

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