Dilute acid hydrolysis of Lignocellulosic biomass

P. Lenihan, Angela Orozco, Eddie O'Neill, Mohamad Ahmad, David Rooney, Gavin Walker

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242 Citations (Scopus)


The overall aim of this work was to establish the optimum conditions for acid hydrolysis of hemicellulosic biomass in the form of potato peel. The hydrolysis reaction was undertaken in a 1l high pressure pilot batch reactor using dilute phosphoric acid. Analysis of the decomposition rate of hemicellulosic biomass (namely Cellulose, Hemicellulose and lignin) was undertaken using HPLC of the reaction products namely, 5 and 6 carbon sugars. Process parameters investigated included, reactor temperature (from 135 degrees C to 200 degrees C) and acid concentration (from 2.5% (w/w) to 10% (w/w)). Analysis of the reactor products indicated that high conversion of cellulose to glucose was apparent although arabinose conversion was quite low due to thermally un-stability. However, an overall sugar yield is 82.5% was achieved under optimum conditions. This optimum yield was obtained at 135 degrees C and 10% (w/w) acid concentration. 55.2 g sugar/100 g dry potato peel is produced after a time of 8 min. The work indicates that the use of potato peel may be a feasible option as a feed material for the production of sugars for biofuel synthesis, due its low cost and high sugar yields. (C) 2009 Elsevier B.V. All rights reserved.
Original languageEnglish
Pages (from-to)395-403
Number of pages9
JournalChemical Engineering Journal
Issue number2
Publication statusPublished - 15 Jan 2010

ASJC Scopus subject areas

  • Chemical Engineering(all)
  • Chemistry(all)
  • Industrial and Manufacturing Engineering
  • Environmental Chemistry

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    Lenihan, P., Orozco, A., O'Neill, E., Ahmad, M., Rooney, D., & Walker, G. (2010). Dilute acid hydrolysis of Lignocellulosic biomass. Chemical Engineering Journal, 156(2), 395-403. https://doi.org/10.1016/j.cej.2009.10.061