Dinitrogen formation over low-exchanged Cu-ZSM-5 in the selective reduction of NO by propane

Evgeny Rebrov; A.V. Simakov; N.N. Sazonova; E.S. Stoyanov

Dinitrogen formation over low-exchanged Cu-ZSM-5 in the selective reduction of NO by propane

Evgeny Rebrov, A.V. Simakov, N.N. Sazonova, E.S. Stoyanov

School of Chemistry and Chemical Engineering

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

The role of gaseous NO and C3H8 has been studied over low-exchanged Cu-ZSM-5 zeolite employing TPD, FTIR and pulse technique with the alternate introduction of NO or C3H8 onto the catalyst surface. The rate of the N-2 formation is directly proportional to the content of gaseous NO and the surface coverage with 2-nitrosopropane. There was no formation of N-2 during interaction of gaseous C3H8 with NO adsorbates. However, 2-nitrosopropane and its isomer acetone oxime were also formed in this reaction.

Original language	English
Pages (from-to)	107-118
Number of pages	12
Journal	Catalysis Letters
Volume	58
Issue number	2-3
Publication status	Published - Apr 1999

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry

Cite this

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title = "Dinitrogen formation over low-exchanged Cu-ZSM-5 in the selective reduction of NO by propane",

abstract = "The role of gaseous NO and C3H8 has been studied over low-exchanged Cu-ZSM-5 zeolite employing TPD, FTIR and pulse technique with the alternate introduction of NO or C3H8 onto the catalyst surface. The rate of the N-2 formation is directly proportional to the content of gaseous NO and the surface coverage with 2-nitrosopropane. There was no formation of N-2 during interaction of gaseous C3H8 with NO adsorbates. However, 2-nitrosopropane and its isomer acetone oxime were also formed in this reaction.",

author = "Evgeny Rebrov and A.V. Simakov and N.N. Sazonova and E.S. Stoyanov",

year = "1999",

month = apr,

language = "English",

volume = "58",

pages = "107--118",

journal = "Catalysis Letters",

publisher = "Springer",

number = "2-3",

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TY - JOUR

T1 - Dinitrogen formation over low-exchanged Cu-ZSM-5 in the selective reduction of NO by propane

AU - Rebrov, Evgeny

AU - Simakov, A.V.

AU - Sazonova, N.N.

AU - Stoyanov, E.S.

PY - 1999/4

Y1 - 1999/4

N2 - The role of gaseous NO and C3H8 has been studied over low-exchanged Cu-ZSM-5 zeolite employing TPD, FTIR and pulse technique with the alternate introduction of NO or C3H8 onto the catalyst surface. The rate of the N-2 formation is directly proportional to the content of gaseous NO and the surface coverage with 2-nitrosopropane. There was no formation of N-2 during interaction of gaseous C3H8 with NO adsorbates. However, 2-nitrosopropane and its isomer acetone oxime were also formed in this reaction.

AB - The role of gaseous NO and C3H8 has been studied over low-exchanged Cu-ZSM-5 zeolite employing TPD, FTIR and pulse technique with the alternate introduction of NO or C3H8 onto the catalyst surface. The rate of the N-2 formation is directly proportional to the content of gaseous NO and the surface coverage with 2-nitrosopropane. There was no formation of N-2 during interaction of gaseous C3H8 with NO adsorbates. However, 2-nitrosopropane and its isomer acetone oxime were also formed in this reaction.

M3 - Article

VL - 58

SP - 107

EP - 118

JO - Catalysis Letters

JF - Catalysis Letters

IS - 2-3

ER -

Dinitrogen formation over low-exchanged Cu-ZSM-5 in the selective reduction of NO by propane

Abstract

ASJC Scopus subject areas

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