Abstract
The X-ray crystal structure of [Pd(eta(3)-allyl)(dppn)]BF4 . CH2Cl2 (1) where dppn = 1,8-bis(diphenylphosphino)naphthalene is reported. Comparison of the conformation of the ligand in 1 with that in the free state shows that there is a relief of strain on complexation analogous to the relief of strain observed upon protonation of proton sponge.
Original language | English |
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Pages (from-to) | 299-301 |
Number of pages | 3 |
Journal | Journal of organometallic chemistry |
Volume | 525 |
Issue number | 1-2 |
Publication status | Published - 1996 |